CAJ | 학술논문

以二-（对烷氧基苯基）乙二酮为原料,经过P2S5硫化、镍络合,合成四-（对甲氧基苯基）硫代双烯合镍和四-（对丁氧基苯基）硫代双烯合镍;讨论硫化时间、硫酸铵用量、五硫化二磷用量对反应收率的影响;利用IR和1H-NMR对这两种硫代双烯型镍配合物的结构进行表征;考察这两种硫代双烯型镍配合物在不同溶剂中的最大吸收波长及其光、热稳定性.
이이-（대완양기분기）을이동위원료,경과P2S5류화、얼락합,합성사-（대갑양기분기）류대쌍희합얼화사-（대정양기분기）류대쌍희합얼;토론류화시간、류산안용량、오류화이린용량대반응수솔적영향;이용IR화1H-NMR대저량충류대쌍희형얼배합물적결구진행표정;고찰저량충류대쌍희형얼배합물재불동용제중적최대흡수파장급기광、열은정성.
In this paper,tetra-（4-methoxy-phenyl） dithiolene nickel complex and tetra-（4-butoxy-phenyl） dithiolene nickel complex were synthesized by sulfuration with P2S5 and nickel complexation by using 1,2-bis-（p-alkoxy-phenyl）-ethanedione as raw material.Factors influencing the reaction yield were discussed,such as sulfuration time,the amount of ammonium sulfate and phosphorus pentasulfide.The structure of dithiolene nickel complexes were characterized by IR and 1H-NMR.The maximum absorption wavelengths of this two dithiolene nickel complexes in different solvent and their photo stability and thermal stability were investiged.