天津城市建设学院学报
天津城市建設學院學報
천진성시건설학원학보
JOURNAL OF TIANJIN INSTITUTE OF URBAN CONSTRUCTION
2011年
4期
260-263
,共4页
高级氧化反应%UV/Fenton%四环素%光氧化
高級氧化反應%UV/Fenton%四環素%光氧化
고급양화반응%UV/Fenton%사배소%광양화
advanced oxidation reaction%UV/Fenton%tetracycline%photo oxidation
分析了FeSO4和H2O2的初始浓度及溶液pH值对UV/Fenton法降解四环素废水的影响.结果表明四环素的初始浓度为25mg/L时,降解四环素的最佳工况:FeS04的初始浓度为0.05mmol/L,H2O2的初始浓度为10mmol/L,pH值为2.5,在反应时间为60min时,对四环素的去除率可达93.14%.另外,对自然光、太阳光、紫外光三种不同光照条件进行了对比试验,得出紫外光辐照下的四环素去除率最高,太阳光次之,自然光最小.
分析瞭FeSO4和H2O2的初始濃度及溶液pH值對UV/Fenton法降解四環素廢水的影響.結果錶明四環素的初始濃度為25mg/L時,降解四環素的最佳工況:FeS04的初始濃度為0.05mmol/L,H2O2的初始濃度為10mmol/L,pH值為2.5,在反應時間為60min時,對四環素的去除率可達93.14%.另外,對自然光、太暘光、紫外光三種不同光照條件進行瞭對比試驗,得齣紫外光輻照下的四環素去除率最高,太暘光次之,自然光最小.
분석료FeSO4화H2O2적초시농도급용액pH치대UV/Fenton법강해사배소폐수적영향.결과표명사배소적초시농도위25mg/L시,강해사배소적최가공황:FeS04적초시농도위0.05mmol/L,H2O2적초시농도위10mmol/L,pH치위2.5,재반응시간위60min시,대사배소적거제솔가체93.14%.령외,대자연광、태양광、자외광삼충불동광조조건진행료대비시험,득출자외광복조하적사배소거제솔최고,태양광차지,자연광최소.
The influences of initial concentrations of the FeSO4, H2O2 and solution pH values on the degradation of tetracycline wastewater by UV/Fenton process were analyzed. Experimental results indicate that when the initial concentration of tetracycline was 25 mg/L, the optimum operational conditions of the processes were as follows: the initial concentration 0.05 mmol/L FeSO4, 10 mmol/L H2O2, pH2.5. After 60 minutes' reaction, the tetracycline removal rate was 93.14%. In addition, comparative tests on varous lighting conditions (natural daylight, sunlight and UV-light) were conducted. The results show that the tetracycline removal rate was highest under UV irradiation, a little lower under sufllight, lowest under natural daylight.