合成技术及应用
閤成技術及應用
합성기술급응용
SYNTHETIC TECHNOLOGY AND APPLICATION
2011年
3期
10-13
,共4页
丙烯腈%丙烯酸%荧光染料%接枝反应%纳米纤维
丙烯腈%丙烯痠%熒光染料%接枝反應%納米纖維
병희정%병희산%형광염료%접지반응%납미섬유
acrylonitrile%acrylic acid%fluorescent dye%graft reaction%nano-fibers
先以丙烯腈和丙烯酸为单体合成聚合物(Polymer-1),用荧光染料对聚合物进行接枝改性后得到聚合物(Polymer-2);然后将这两种聚合物通过静电纺丝法制备出纳米纤维毡。研究了单体配比对Polymer-1共聚物粘均分子质量的影响;用DSC和IR测试手段对聚合物结构进行表征,用SEM和荧光光谱分析(FS)测试手段对纳米纤维毡的微观形状和荧光性能进行测试。结果表明,成功制备出荧光改性聚合物Polymer-2,获得了具有荧光性能的纳米纤维毡。
先以丙烯腈和丙烯痠為單體閤成聚閤物(Polymer-1),用熒光染料對聚閤物進行接枝改性後得到聚閤物(Polymer-2);然後將這兩種聚閤物通過靜電紡絲法製備齣納米纖維氈。研究瞭單體配比對Polymer-1共聚物粘均分子質量的影響;用DSC和IR測試手段對聚閤物結構進行錶徵,用SEM和熒光光譜分析(FS)測試手段對納米纖維氈的微觀形狀和熒光性能進行測試。結果錶明,成功製備齣熒光改性聚閤物Polymer-2,穫得瞭具有熒光性能的納米纖維氈。
선이병희정화병희산위단체합성취합물(Polymer-1),용형광염료대취합물진행접지개성후득도취합물(Polymer-2);연후장저량충취합물통과정전방사법제비출납미섬유전。연구료단체배비대Polymer-1공취물점균분자질량적영향;용DSC화IR측시수단대취합물결구진행표정,용SEM화형광광보분석(FS)측시수단대납미섬유전적미관형상화형광성능진행측시。결과표명,성공제비출형광개성취합물Polymer-2,획득료구유형광성능적납미섬유전。
In this paper,Polymer-1 was synthesized by acrylonitrile monomer and acrylic monomer,and polymer-2 was the modified product when polymer-1 was grafted with fluorescent dyes.Then two polymers' nano-fiber mats were prepared through electrospinning process(ESP).The influence of the monomer ratio on Polymer-1's viscosity average molecular weight was studied.DSC and IR were used to characterize the polymer firstly,SEM and Single-photon fluorescence spectra(FS) were used to test the nano-fiber mats.The results demonstrate that the fluorescent copolymer(Polymer-2 ) was prepared successfully and nano-fiber mats with fluorescent properties could be obtained using ESP technology.