无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2007年
10期
1809-1811
,共3页
董文魁%宋学琴%孙银霞%吴辉禄
董文魁%宋學琴%孫銀霞%吳輝祿
동문괴%송학금%손은하%오휘록
钾(Ⅰ)配合物%合成%晶体结构
鉀(Ⅰ)配閤物%閤成%晶體結構
갑(Ⅰ)배합물%합성%정체결구
potassium(Ⅰ) complex%synthesis%crystal structure
A supramolecular complex, [Kpic]n (picˉ is picratol, (NO2)3C6H2Oˉ), has been synthesized unexpectedly in acetone solution, and characterized by elemental analysis, IR and X-ray crystallography. In the complex, the ions. The coordination number of every potassium atom is eight. Interestingly, the picratol adopts an eightcoordinated ideal mode unreported. CCDC: 630627.
