结构化学
結構化學
결구화학
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2005年
2期
159-162
,共4页
zinc%thiocyanate%crystal structure%photoluminescence
The hydrothermal reaction of thiocyanate, 2,2'-bipyridine and ZnⅡ in basified
aqueous solutions gave rise to complex [Zn(bipy)3][Zn(SCN)4] 1 (C34H24N1oS4Zn2) which was
characterized by X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, Mr=
831.61, Z= 4, a = 15.920(3), b = 13.5201(17), c = 17.362(3) (A), β= 99.467(9)°, V= 3686.1(10) (A)3,
Dc= 1.499 g/cm3, μ = 1.568 mm-1, F(000) = 1688, R = 0.0586 and wR = 0.1354 for 5604 observed
reflections (I ＞ 2σ(I)). The photoluminescence spectrum for the title compound has also been
studied.
