湖泊科学
湖泊科學
호박과학
JOURNAL OF LAKE SCIENCES
2001年
1期
9-14
,共6页
瞿文川%王苏民%吴瑞金%张平中%崔明中
瞿文川%王囌民%吳瑞金%張平中%崔明中
구문천%왕소민%오서금%장평중%최명중
太湖沉积物多环芳烃菲来源识别
太湖沉積物多環芳烴菲來源識彆
태호침적물다배방경비래원식별
本文用索氏抽取法提取了东太湖的沉积物和水生植物中的可溶性有机质,用不同极性溶剂在硅胶/氧化铝柱上分离了饱和烃、芳烃、酮馏分,利用GC-MS对芳烃组分进行了鉴定分析,并对其中重要多环芳烃-菲系列化合物的来源进行了探讨。
本文用索氏抽取法提取瞭東太湖的沉積物和水生植物中的可溶性有機質,用不同極性溶劑在硅膠/氧化鋁柱上分離瞭飽和烴、芳烴、酮餾分,利用GC-MS對芳烴組分進行瞭鑒定分析,併對其中重要多環芳烴-菲繫列化閤物的來源進行瞭探討。
본문용색씨추취법제취료동태호적침적물화수생식물중적가용성유궤질,용불동겁성용제재규효/양화려주상분리료포화경、방경、동류분,이용GC-MS대방경조분진행료감정분석,병대기중중요다배방경-비계렬화합물적래원진행료탐토。
There has been a growing concern in recent years regarding possible harmful effects to man and other living organisms of pollutant organic chemicals released into the environment as a consequence of human activities. Polycyclic aromatic hydrocarbons (PAHs) are one of the more significant classes of pollutants, which give rise to this concern. This concern arises primarily from the fact that some PAHs generated and released to the environment by human activities have shown to be carcinogenic to mammals. Many researches have been done about the properties of PAHs.PAHs of different molecular weights or structures vary substantially in their behavior and distribution in the environment and their effects on biological systems. PAHs can be formed mainly in three ways: high temperature pyrolysis of organic materials, low to moderate temperature diagensis of sedimentary organic material to form fossil fuels, and direct biogenesis by microbes and plants.
In this paper, the extractable lipids were isolated using Soxhlet extraction method in the East Taihu Lake sediment, the extracts were fractionated on an activated SiO2/Al2O3 column. The aromatic compounds were washed in benzene. Phenanthrene series, one group of important polycyclic aromatic hydrocarbons were analyzed and identified by the GC - MS instrument. The sources of Phenanthrene in Taihu Lake sediment were discussed. Phenanthrene series were also found from the aquatic plants with similar composition pattern with that in the East Taihu Lake sediment. This is the first time that aquatic plants have been singled out as the major source of phenanthrene series in the East Taihu Lake sediments.