GaxCs2.5-3xH0.5PW12O40的固相法制备及其催化正丁烷异构化反应的活性
GaxCs2.5-3xH0.5PW12O40적고상법제비급기최화정정완이구화반응적활성
Solid Synthesis of GaxCs2.5-3xH0.5PW12O40 Salts and Their Catalytic Activity in the Isomerization of n-Butane
  • 万方数据
    催化学报 최화학보
    CHINESE JOURNAL OF CATALYSIS
    2011年 4期 521-524 ,共4页

    张丽%岳斌%冯素姣%钱林平%贺鹤勇

    장려%악빈%풍소교%전림평%하학용

    镓%钨磷酸铯盐%固相合成%正丁烷异构化%酸性 鎵%鎢燐痠銫鹽%固相閤成%正丁烷異構化%痠性
    가%오린산색염%고상합성%정정완이구화%산성
    gallium%cesium salt of tungstophosphoric acid%solid synthesis%butane isomerization%acidity
    利用室温固相法制备了一系列掺镓的钨磷酸铯盐催化剂GaxCs2.5-3xH0.5PW12O40(x=0.05,0.1,0.15).与钨磷酸铯盐相比,掺镓的钨磷酸铯盐催化剂的结构未产生变化,但其酸强度提高,在正丁烷异构化反应中催化活性增强,其中以Ga0.1Cs2.2H0.5PW12O40和Ga0.15Cs2.05H0.5PW12O40最为显著.
    이용실온고상법제비료일계렬참가적오린산색염최화제GaxCs2.5-3xH0.5PW12O40(x=0.05,0.1,0.15).여오린산색염상비,참가적오린산색염최화제적결구미산생변화,단기산강도제고,재정정완이구화반응중최화활성증강,기중이Ga0.1Cs2.2H0.5PW12O40화Ga0.15Cs2.05H0.5PW12O40최위현저.
    GaxCs2.5-3xH0.5PWl2O40(x=0.05, 0.10, and 0.15) salts were prepared using a solid synthesis method and they showed higher catalytic activity than that of Cs2.5H0.5PW12O40 for n-butane isomerization, which possibly comes from their enhanced acid strength as a result of Ga doping.
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