CAJ | 학술논문

制备了含锰、铬、钼、钒的取代磷钨杂多酸，采用红外、X-射线衍射、ICP对制备的化合物进行了分析及表征，结果表明，制备所得化合物是Keggin结构的杂多酸。研究了这些杂多酸催化合成苯甲醛乙二醇缩醛，在催化剂的用量为反应物总质量的2．0％，反应温度为120℃，反应时间为1h的条件下，苯甲醛乙二醇缩醛的收率可达72．5％。
제비료함맹、락、목、범적취대린오잡다산，채용홍외、X-사선연사、ICP대제비적화합물진행료분석급표정，결과표명，제비소득화합물시Keggin결구적잡다산。연구료저사잡다산최화합성분갑철을이순축철，재최화제적용량위반응물총질량적2．0％，반응온도위120℃，반응시간위1h적조건하，분갑철을이순축철적수솔가체72．5％。
The heteropoly acids contained manganese, chromium, molybdenum, and vanadium were prepared, which was characterized by IR, XRD and ICP, and revealed that the compounds synthesized in the present work were Keggin structure. The catalytic performance of the heteropoly acids for the synthesis of benzaldehyde glycol acetal were in- vestigated, under the reaction condition of reaction temperature 120℃, amount of catalyst 2.0% , reaction time 1 h, and the yield of benzaldehyde glycol acetal can obtain to 72.5%.