CAJ | 학술논문

分析了利用溶胶-凝胶法制备ZAO粉体时,干燥温度,煅烧温度,乙醇与水的比例,主盐浓度,氧化铝与氧化锌的比例对其晶体结的构和形态的影响。利用X-射线衍射仪、扫描电镜等对得到的ZAO粉体进行了分析和表征。结果表明,煅烧温度对ZAO的晶体的结构和形态有重要影响,煅烧温度高于850℃时能成功地对ZnO进行铝的掺杂,而乙醇与水的比例对试样的晶形也有一定的影响,醋酸锌、柠檬酸三铵浓度及铝掺杂量对ZAO的影响最弱。
분석료이용용효-응효법제비ZAO분체시,간조온도,단소온도,을순여수적비례,주염농도,양화려여양화자적비례대기정체결적구화형태적영향。이용X-사선연사의、소묘전경등대득도적ZAO분체진행료분석화표정。결과표명,단소온도대ZAO적정체적결구화형태유중요영향,단소온도고우850℃시능성공지대ZnO진행려적참잡,이을순여수적비례대시양적정형야유일정적영향,작산자、저몽산삼안농도급려참잡량대ZAO적영향최약。
Super fine ZAO powders were prepared by sol-gel method in different conditions.Effect of drying temperature,sinter temperature,the proportion of ethanol to water,the concentration of（CH3COO）2Zn？2H2O,the proportion of AlO to ZnO on the crystal form of ZAO powders was discussed.The powders were analyzed by XRD,TEM etc.The result show that,firing temperature have significant effect on the crystal form of ZAO,and at 850℃,ZnO successfully adulterated by Al.The proportion of ethanol in water can effect the crystal also,but the concentration of（CH3COO）2Zn？2H2O,（NH4）3C6H5O7 and Al have little effect on ZAO crystal form.