CAJ | 학술논문

主要阐述了近年来离子液体作为溶剂、单体或者配位剂在原子转移自由基聚合中的应用研究情况.从对聚合反应速率的大小的影响,聚合产物分子量多分散系数的变化,聚合物分子链功能性的设计,以及反应体系中催化体系的分离与循环使用等方面总结了离子液体的参与对原子转移自由基聚合的影响,并简要总结了导致各种变化的原因.最后展望了离子液体应用于原子转移自由基聚合技术的前景,并指出离子液体自身研究的发展是二者结合的关键问题.
주요천술료근년래리자액체작위용제、단체혹자배위제재원자전이자유기취합중적응용연구정황.종대취합반응속솔적대소적영향,취합산물분자량다분산계수적변화,취합물분자련공능성적설계,이급반응체계중최화체계적분리여순배사용등방면총결료리자액체적삼여대원자전이자유기취합적영향,병간요총결료도치각충변화적원인.최후전망료리자액체응용우원자전이자유기취합기술적전경,병지출리자액체자신연구적발전시이자결합적관건문제.
Recent developments on the application of ionic liquids (ILs) in atom transfer radical polymerization (ATRP) are reviewed.Particular emphasis is placed on the significant effect on the performance of the polymers,including well-controlled process with predictable molecular weight,narrow polydispersity,and well-defined architecture,if the ionic liquids were used as solvent,initiator,ligand or monomer.And a discussion on the opportunities of ionic liquids used in atom transfer radical polymerization for the future concludes this review as well.