结构化学
結構化學
결구화학
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2001年
2期
97-99
,共3页
A mix-charge cation solid-state borate oxide Co3BO5 has beensynthesized and its structure has been determined by single-crystal X-ray methods. It crystallizes in the orthorhombic～space group Pbam with cell parameters a=9.2963(2), b=11.948(2), c=2.9737(6) Å, V=330.30(12)Å3, Z=4, Mr=267.60, F(000)=504, μ=14.733, Dcalcd=5.381g/cm3. The structure was determined from 853 unique reflections and refined to the final residuals R=0.0633 and wR=0.1457. It has two kinds of Co cations, Co2+ and Co3+. It is composed of highly distorted [CoO4] squares and triangular [BO3] groups that are connected to form infinite two-dimensional layers.
