CAJ | 학술논문

在实验室以镁铝氧化物固溶体(Mg(Al)O)固体碱负载磺化酞菁钴(CoSPc)制成的双功能催化剂，对硫醇氧化反应具有良好的催化活性。载体的碱性强弱、催化剂制备过程中使用的溶剂种类及催化剂中溶剂的含量对催化剂活性有显著影响。不同结构硫醇氧化反应结果表明，大分子、异构硫醇较难氧化。此外，利用双功能催化剂进行了小型固定床喷气燃料脱臭试验，取得了初步成果。
재실험실이미려양화물고용체(Mg(Al)O)고체감부재광화태정고(CoSPc)제성적쌍공능최화제 ， 대류순양화반응구유량호적최화활성。재체적감성강약、최화제제비과정중사용적용제 충류급최화제중용제적함량대최화제활성유현저영향。불동결구류순양화반응결과표명， 대분자、이구류순교난양화。차외， 이용쌍공능최화제진행료소형고정상분기연료탈취시 험， 취득료초보성과。
Bifunctional catalyst using Mg /Al oxide solid solution as carrier impregnated with cobalt phthalocyanine sulfo nates (CoSPc) was prepared in the laboratory. The test result showed that the sa id catalyst had good catalytic activity. The basicity of the carrier, and the im pregnated solvents and their amounts remained in the catalyst could greatly infl uence the catalyst activity. Different structure thiols oxidation indicated the macromolecular and isostructure thiols were difficult to be oxidized. The jet fu el sweetening conducted on a fixed bed reactor over the said catalyst showed goo d result.