河北大学学报(自然科学版)
河北大學學報(自然科學版)
하북대학학보(자연과학판)
JOURNAL OF HEBEI NORMAL UNIVERSITY
2003年
1期
93-95
,共3页
杜建龙%韩玲芹%李记太%崔勇%孙文华
杜建龍%韓玲芹%李記太%崔勇%孫文華
두건룡%한령근%리기태%최용%손문화
2,6-二亚胺基苯酚%钴、镍%配合物
2,6-二亞胺基苯酚%鈷、鎳%配閤物
2,6-이아알기분분%고、얼%배합물
2,6 - Bis(imino) phenoxy%cobalt and nickel%complexes
在乙醇溶剂中冰醋酸催化下,2-羟基-5-叔丁基-1,3-亚苯基二甲醛和相应的取代苯胺缩合得到74.6%~85.7%的双席夫碱配体.将配体分别与CoCl2@6H2O和NiCl2@6H2O反应,得到6个配合物,收率74.1%~85.2%.合成路线简单易行,产率高.
在乙醇溶劑中冰醋痠催化下,2-羥基-5-叔丁基-1,3-亞苯基二甲醛和相應的取代苯胺縮閤得到74.6%~85.7%的雙席伕堿配體.將配體分彆與CoCl2@6H2O和NiCl2@6H2O反應,得到6箇配閤物,收率74.1%~85.2%.閤成路線簡單易行,產率高.
재을순용제중빙작산최화하,2-간기-5-숙정기-1,3-아분기이갑철화상응적취대분알축합득도74.6%~85.7%적쌍석부감배체.장배체분별여CoCl2@6H2O화NiCl2@6H2O반응,득도6개배합물,수솔74.1%~85.2%.합성로선간단역행,산솔고.
The 2,6 - bis(imino) phenoxy ligands were prepared in 74.6 % ~ 85.7 % yield by the condensa-tion of the appropriate aniline with 2 - hydroxy - 5 - tert - butyl - isophthaldehyde. A series of new cobalt andnickel complexes LMX2(M = Co, X = Cl; M = Ni, X= Cl) bearing 2,6 - bis(imino)phenoxy ligands were syn-thesized in yield 74.1% ~ 85.2 %.