矿物岩石地球化学通报
礦物巖石地毬化學通報
광물암석지구화학통보
BULLETIN OF MINERALOGY PETROLOGY AND GEOCHEMISTRY
2009年
4期
365-376
,共12页
祝朝辉%刘淑霞%张乾%邵树勋%谷德敏
祝朝輝%劉淑霞%張乾%邵樹勛%穀德敏
축조휘%류숙하%장건%소수훈%곡덕민
白牛厂银多金属矿床%喷流沉积%岩浆热液叠加改造%稀土元素
白牛廠銀多金屬礦床%噴流沉積%巖漿熱液疊加改造%稀土元素
백우엄은다금속광상%분류침적%암장열액첩가개조%희토원소
Bainiuchang polymetallic deposit%exhalative sedimentary%magmatac hydrothermal superimposition%rare earth element
为了研究白牛厂银多金属矿床成矿作用特征,对矿区岩浆岩、围岩和矿石的稀土元素进行了ICP-MS分析测试.花岗岩稀土元素组成表现了较强的Eu负异常和弱的Ce负异常.围岩稀土元素特征表现出一定程度的热水沉积成因.矿石的稀土元素组成大致可分为两组:一组矿石表现为Eu正异常或无异常和Ce负异常,反映喷流沉积稀土元素组成特征,主要是距离花岗岩体较远的白羊矿段,指示成矿热液为温度较高(>250℃)、相对还原的流体,另外,Eu正异常和Ce负异常同时出现,说明矿石沉淀时较高温度的流体与少量的海水发生了对流混合;另一组矿石表现出与岩浆岩一致的球粒陨石标准化稀土配分模式,显示岩浆热液叠加改造成因,主要是距离花岗岩体较近的穿心洞矿段和对门山矿段.两组矿石稀土元素组成特征总体来说随着花岗岩体距离的变化而变化.根据岩浆岩、围岩和矿石的稀土元素组成特征,白牛厂银多金属矿床由喷流沉积形成主矿体,燕山期花岗质岩浆活动对矿体部分叠加改造.
為瞭研究白牛廠銀多金屬礦床成礦作用特徵,對礦區巖漿巖、圍巖和礦石的稀土元素進行瞭ICP-MS分析測試.花崗巖稀土元素組成錶現瞭較彊的Eu負異常和弱的Ce負異常.圍巖稀土元素特徵錶現齣一定程度的熱水沉積成因.礦石的稀土元素組成大緻可分為兩組:一組礦石錶現為Eu正異常或無異常和Ce負異常,反映噴流沉積稀土元素組成特徵,主要是距離花崗巖體較遠的白羊礦段,指示成礦熱液為溫度較高(>250℃)、相對還原的流體,另外,Eu正異常和Ce負異常同時齣現,說明礦石沉澱時較高溫度的流體與少量的海水髮生瞭對流混閤;另一組礦石錶現齣與巖漿巖一緻的毬粒隕石標準化稀土配分模式,顯示巖漿熱液疊加改造成因,主要是距離花崗巖體較近的穿心洞礦段和對門山礦段.兩組礦石稀土元素組成特徵總體來說隨著花崗巖體距離的變化而變化.根據巖漿巖、圍巖和礦石的稀土元素組成特徵,白牛廠銀多金屬礦床由噴流沉積形成主礦體,燕山期花崗質巖漿活動對礦體部分疊加改造.
위료연구백우엄은다금속광상성광작용특정,대광구암장암、위암화광석적희토원소진행료ICP-MS분석측시.화강암희토원소조성표현료교강적Eu부이상화약적Ce부이상.위암희토원소특정표현출일정정도적열수침적성인.광석적희토원소조성대치가분위량조:일조광석표현위Eu정이상혹무이상화Ce부이상,반영분류침적희토원소조성특정,주요시거리화강암체교원적백양광단,지시성광열액위온도교고(>250℃)、상대환원적류체,령외,Eu정이상화Ce부이상동시출현,설명광석침정시교고온도적류체여소량적해수발생료대류혼합;령일조광석표현출여암장암일치적구립운석표준화희토배분모식,현시암장열액첩가개조성인,주요시거리화강암체교근적천심동광단화대문산광단.량조광석희토원소조성특정총체래설수착화강암체거리적변화이변화.근거암장암、위암화광석적희토원소조성특정,백우엄은다금속광상유분류침적형성주광체,연산기화강질암장활동대광체부분첩가개조.
This paper investigated the mineralization characteristics of sea-floor exhalative sedimentation and magmatic hydrothermal superimposition on the Bainiuchang ploymetallic deposit by systematically analyzing the REE compositions of granites, host-rocks and ores in the deposit area using ICP-MS. The REE compositions of granites possess obvious negative Eu anomalies and weak negative Ce anomalies; the REE characteristics of host-rocks imply they derived partly from sea-floor exhalative sedimentary. According to their REE compositions, the ores can be separated into two groups: one group, collected in Baiyang segment, a segment locates relatively further from the Bozhushan granite matrix, possesses none to positive Eu anomalies and negative Ce anomalies. This ore group represents that the ore-forming hydrothermal fluid is relatively reductive and its temperature is higher than 250℃. The co-occurrence of positive Eu anomalies and negative Ce anomalies indicates that convective mixing of a small amount of seawater with the hydrothermal fluid may have happened during ore depositing on the ancient seafloor. The other group, mainly collected from Chuanxindong and Duimenshan segments, segments locates relatively closer to the Bozhushan granite matrix, has similar chondrite-normalized REE distribution pattern to that of the granite. In addition to above differences, the REE characteristics of both groups of ores vary gradually by the distances of the collecting locations to the Bozhushan granite matrix. Based on REE characteristics of the Bainiuchang Ag-polymetallic deposit, we believe that the main ore body was formed by exhalative sedimentations and was partially superimposed by the Yanshanian granitic magma activites.