CAJ | 학술논문

用分层法合成了两个配合物[Ag2(L)2](CF3COO)2(1)和[Ag2(L)2](CF3SO3)2(2)[L=2-甲基4,6-二(3-吡啶基)嘧啶],并用元素分析、红外光谱、X-射线单晶衍射等手段对其进行了表征.晶体结构分析结果表明:具有双核大环结构的配合物1和2由Ag(I)…Ag(I)相互作用连接形成一维链状结构,并进一步通过π-π相互作用形成二维层状结构.研究了配合物2的荧光性质.
용분층법합성료량개배합물[Ag2(L)2](CF3COO)2(1)화[Ag2(L)2](CF3SO3)2(2)[L=2-갑기4,6-이(3-필정기)밀정],병용원소분석、홍외광보、X-사선단정연사등수단대기진행료표정.정체결구분석결과표명:구유쌍핵대배결구적배합물1화2유Ag(I)…Ag(I)상호작용련접형성일유련상결구,병진일보통과π-π상호작용형성이유층상결구.연구료배합물2적형광성질.
Two silver(I) complexes [Ag2(L)2](CF3COO)2 (1) and [Aga(L)2](CF3SO3)2 (2) [L=2-methyl-4,6-di(pyridin-3-yl)pyrimidine] were synthesized and characterized by elemental,IR and single crystal X-ray diffraction analyses.The binuclear complexes 1 and 2 form infinite 1D chains through argentophilic interactions,and further extend into 2D supramolecular networks by π-π interactions.The photoluminescent measurements reveal that complex 2exhibits fluorescent emission in the solid state at room temperature and the luminescent decay time was determined.CCDC; 827908,1; 827909,2.