材料科学与工程学报
材料科學與工程學報
재료과학여공정학보
MATERIALS SCIENCE AND ENGINEERING
2007年
6期
906-909
,共4页
光致发光%La2(MoO4)3∶Eu%水热法
光緻髮光%La2(MoO4)3∶Eu%水熱法
광치발광%La2(MoO4)3∶Eu%수열법
Photoluminescence%lanthanide molybdate%hydrothermal method
在表面活性剂十二烷基硫酸钠(SDS)的作用下,采用温和的水热方法,成功制备了Eu掺杂的花瓣状La2(MoO4)3∶Eu纳米微结构.这些形貌新颖的微米绒球的直径约3μm,由厚度30nm左右的纳米片次级结构单元自组装构筑而成,分散性良好,形貌规整、大小均一.通过XRD、SEM、TEM测试技术,研究了形貌的形成机理.由于具有良好的结晶度,这些花瓣状La2(MoO4)3∶Eu纳米微结构显示出良好的发光性能.
在錶麵活性劑十二烷基硫痠鈉(SDS)的作用下,採用溫和的水熱方法,成功製備瞭Eu摻雜的花瓣狀La2(MoO4)3∶Eu納米微結構.這些形貌新穎的微米絨毬的直徑約3μm,由厚度30nm左右的納米片次級結構單元自組裝構築而成,分散性良好,形貌規整、大小均一.通過XRD、SEM、TEM測試技術,研究瞭形貌的形成機理.由于具有良好的結晶度,這些花瓣狀La2(MoO4)3∶Eu納米微結構顯示齣良好的髮光性能.
재표면활성제십이완기류산납(SDS)적작용하,채용온화적수열방법,성공제비료Eu참잡적화판상La2(MoO4)3∶Eu납미미결구.저사형모신영적미미융구적직경약3μm,유후도30nm좌우적납미편차급결구단원자조장구축이성,분산성량호,형모규정、대소균일.통과XRD、SEM、TEM측시기술,연구료형모적형성궤리.유우구유량호적결정도,저사화판상La2(MoO4)3∶Eu납미미결구현시출량호적발광성능.
Three-dimensional flowerlike europium doped lanthanide molybdate (La2 (MoO4)3: Eu) micro-architectures, which exhibit efficient photoluminescence, have been successfully synthesized via a facile hydrothermal process in the presence of the surfactant sodium dodecylsulfate (shortened title: SDS). These microspheres are well dispersed and have a uniform diameter of about 3μm, and are composed of secondary structures-nanoflakes with thickness of about 30nm. The structure was characterized by XRD, SEM and TEM, and the possible action mechanism of the surfactant is preliminarily investigated. These La2(MoO4)3: Eu microspheres show efficient photoluminescence which is associated with the well crystallized structures of the micro-architectures.