无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2009年
3期
567-570
,共4页
王作祥%宫晓宁%瞿志荣%吴平锋%张晓明
王作祥%宮曉寧%瞿誌榮%吳平鋒%張曉明
왕작상%궁효저%구지영%오평봉%장효명
铜(Ⅱ)配合物%晶体结构%荧光性质
銅(Ⅱ)配閤物%晶體結構%熒光性質
동(Ⅱ)배합물%정체결구%형광성질
copper(Ⅱ) complex%crystal structure%fluorescence
A copper(Ⅱ) complex [CuL(H2O)(Sal)]·0.5H2O was obtained by the reaction of eopper(Ⅱ) salieylate with 3-methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole (L) in ethanol-water solution at room temperature. The crystal belongs to triclinic system with space group P1, and a=0.913 6(4) nm, b=1.122 2(5) nm, c=1.263 3(7) nm, α=67.10(2)°, β=76.31(3)°,γ=68.17(2)°, V= 1.101(1) nm3, Z=2. The final refinement gave R1=0.039 8 and wR2=0.106 0for 3 453 reflections with I2σ(I). This complex is a good purple fluorescent material in solid state at room temperat-ttre. CCDC: 685713.
