功能材料与器件学报
功能材料與器件學報
공능재료여기건학보
JOURNAL OF FUNCTIONAL MATERIALS AND DEVICES
2001年
3期
235-239
,共5页
何贤昶%沈荷生%张志明%胡晓君%杨小倩%万永中
何賢昶%瀋荷生%張誌明%鬍曉君%楊小倩%萬永中
하현창%침하생%장지명%호효군%양소천%만영중
CVD金刚石%涂层%丝%纤维
CVD金剛石%塗層%絲%纖維
CVD금강석%도층%사%섬유
用CVD方法在钨丝和碳纤维上沉积金刚石薄膜。约含有10000根纤维的纤维束经特殊
处理后分离为单根。生长条件使碳纤维中心在CVD生长结束后仍保持固态。CVD金刚石在纤
维上生长的平均激活能为93.15kJ/mol。SEM照片给出了纤维涂层在不同生长条件下的表面和
中心的形貌。纤维内部的石墨碳和外部的金刚石层有很大的不同。钨丝的断裂强度和杨氏模量
的测量表明,具有金刚石涂层的钨丝的断裂强度为0.567GPa,非常接近不具有金刚石涂层的钨
丝的断裂强度。但具有金刚石涂层的钨丝的断裂应变为4.8%,比没有金刚石涂层的钨丝的断
裂应变7%要小得多。这表明了金刚石涂层可以减少钨丝的断裂应力,提高其机械性能。
用CVD方法在鎢絲和碳纖維上沉積金剛石薄膜。約含有10000根纖維的纖維束經特殊
處理後分離為單根。生長條件使碳纖維中心在CVD生長結束後仍保持固態。CVD金剛石在纖
維上生長的平均激活能為93.15kJ/mol。SEM照片給齣瞭纖維塗層在不同生長條件下的錶麵和
中心的形貌。纖維內部的石墨碳和外部的金剛石層有很大的不同。鎢絲的斷裂彊度和楊氏模量
的測量錶明,具有金剛石塗層的鎢絲的斷裂彊度為0.567GPa,非常接近不具有金剛石塗層的鎢
絲的斷裂彊度。但具有金剛石塗層的鎢絲的斷裂應變為4.8%,比沒有金剛石塗層的鎢絲的斷
裂應變7%要小得多。這錶明瞭金剛石塗層可以減少鎢絲的斷裂應力,提高其機械性能。
용CVD방법재오사화탄섬유상침적금강석박막。약함유10000근섬유적섬유속경특수
처리후분리위단근。생장조건사탄섬유중심재CVD생장결속후잉보지고태。CVD금강석재섬
유상생장적평균격활능위93.15kJ/mol。SEM조편급출료섬유도층재불동생장조건하적표면화
중심적형모。섬유내부적석묵탄화외부적금강석층유흔대적불동。오사적단렬강도화양씨모량
적측량표명,구유금강석도층적오사적단렬강도위0.567GPa,비상접근불구유금강석도층적오
사적단렬강도。단구유금강석도층적오사적단렬응변위4.8%,비몰유금강석도층적오사적단
렬응변7%요소득다。저표명료금강석도층가이감소오사적단렬응력,제고기궤계성능。
Diamond growth on W-wire and C-fiber substrates was studied. A treatment was used to
separate fibers one by one from a bunch of more than 10000 fibers. The selected growth condition
was to keep the carbon fiber core solid after CVD growth. Activation energy of CVD coated fibers is
93.15 kJ/mol in average. SEM pictures show surface and core morphology of the coatings under
different treatment conditions. There are two different contrasts related to interior graphite carbon and
exterior diamond layer. Wire fracture strength and Young's modulus measurement indicates that the
fracture strength of W wire with diamond coating is 0.567 GPa, very close to its value without coating.
However, the fracture strain of the wire with diamond coating is 4.8% , which is much less than that
of W wire fracture strain of 7% . It means that diamond coated wire may reduce wire fracture strain
and improve its mechanical property.