高分子材料科学与工程
高分子材料科學與工程
고분자재료과학여공정
POLYMER MATERIALS SCIENCE & ENGINEERING
2001年
3期
157-159
,共3页
田明%李齐方%张立群%刘力%乔利燕%吕昆%沙中瑛
田明%李齊方%張立群%劉力%喬利燕%呂昆%沙中瑛
전명%리제방%장립군%류력%교리연%려곤%사중영
ABS%合金%耐热%改性剂
ABS%閤金%耐熱%改性劑
ABS%합금%내열%개성제
以ABS树脂为基体,加入短玻璃纤维提高了材料的耐热性,但冲击强度下降,进一步引入与ABS相容性很好的苯乙烯-马来酸酐共聚物(SMA),发现ABS与玻璃纤维间产生了强有力的界面粘合,在SMA含量7%时,显著地提高了ABS/玻纤体系的耐热性、冲击强度和拉伸强度。再进一步引入适量的刚性丙烯酸酯类聚合物,使ABS/玻纤/SMA体系的耐热性又有所提高。令人惊奇的是,在丙烯酸酯类聚合物含量为30%时,体系的冲击性能也明显增加,这归功于刚性有机填料对体系的冷拉增韧效果。最终成功研制出一种高耐热、综合性能优良的ABS/改性剂/玻纤共混合金。
以ABS樹脂為基體,加入短玻璃纖維提高瞭材料的耐熱性,但遲擊彊度下降,進一步引入與ABS相容性很好的苯乙烯-馬來痠酐共聚物(SMA),髮現ABS與玻璃纖維間產生瞭彊有力的界麵粘閤,在SMA含量7%時,顯著地提高瞭ABS/玻纖體繫的耐熱性、遲擊彊度和拉伸彊度。再進一步引入適量的剛性丙烯痠酯類聚閤物,使ABS/玻纖/SMA體繫的耐熱性又有所提高。令人驚奇的是,在丙烯痠酯類聚閤物含量為30%時,體繫的遲擊性能也明顯增加,這歸功于剛性有機填料對體繫的冷拉增韌效果。最終成功研製齣一種高耐熱、綜閤性能優良的ABS/改性劑/玻纖共混閤金。
이ABS수지위기체,가입단파리섬유제고료재료적내열성,단충격강도하강,진일보인입여ABS상용성흔호적분을희-마래산항공취물(SMA),발현ABS여파리섬유간산생료강유력적계면점합,재SMA함량7%시,현저지제고료ABS/파섬체계적내열성、충격강도화랍신강도。재진일보인입괄량적강성병희산지류취합물,사ABS/파섬/SMA체계적내열성우유소제고。령인량기적시,재병희산지류취합물함량위30%시,체계적충격성능야명현증가,저귀공우강성유궤전료대체계적랭랍증인효과。최종성공연제출일충고내열、종합성능우량적ABS/개성제/파섬공혼합금。
The addition of short glass fiber into ABS resin can improve its heat resistance but decrease its impact strength. It is discovered that strong interphase adhesion between ABS and glass fiber can be gotten by the introduction of styrene-maleic anhydride copolymer(SMA) which is completely compatible with ABS, and heat resistance, impact strength and tensile strength of ABS/glass fiber alloy can be improved remarkably when the content of SMA is 7%. Subsequently, the introduction of 30% rigid acrylic ester polymer into above system can further improve heat resistance of ABS/glass fiber/SMA. Surprisingly, its impact strength is also enhanced, which is attributed to the hard-drawn mechanism of rigid organic filler (ROF). At last, a kind of ABS blend alloys with high heat resistance and good mechanical properties are successfully made.