CAJ | 학술논문

以1,3-丙二胺为模板剂,在溶剂热条件下合成了两个一维磷酸盐微孔分子筛:[GaP2O7(OH)][NH3(CH2)3NH3](1)和[Ge0.5GaP1.5O6.5(OH)1.5][NH3(CH2)3NH3](2).X射线单晶结构解析表明,两个晶体结构分别由镓氧四面体和磷氧四面体,或镓氧四面体、锗氧四面体和磷氧四面体组成,并沿层c轴方向形成链.这些链之间由1,3-丙二胺相连.1的结晶学数据为Mr=331.82,P-1,a=0.8303(2)nm,b=0.8614(3)nm,c=0.8880(2)nm,α=111.70(3)°,β=107.59(2)°,γ=98.39(2)°,V=0.5382(3)nm3,Z=1,MoKα,λ=0.071073nm,R(F)=5.56%,wR(F2)=14.36%.2的结晶学数据为:P2(1)/c,a=0.88968(7)nm,b=1.67562(13)nm,c=0.83666(7)nm,β=115.890(2),V=1.12208(16)nm3,Z=4,Mo Kα,R(F)=4.66%,wR(F2)=10.10%.
이1,3-병이알위모판제,재용제열조건하합성료량개일유린산염미공분자사:[GaP2O7(OH)][NH3(CH2)3NH3](1)화[Ge0.5GaP1.5O6.5(OH)1.5][NH3(CH2)3NH3](2).X사선단정결구해석표명,량개정체결구분별유가양사면체화린양사면체,혹가양사면체、타양사면체화린양사면체조성,병연층c축방향형성련.저사련지간유1,3-병이알상련.1적결정학수거위Mr=331.82,P-1,a=0.8303(2)nm,b=0.8614(3)nm,c=0.8880(2)nm,α=111.70(3)°,β=107.59(2)°,γ=98.39(2)°,V=0.5382(3)nm3,Z=1,MoKα,λ=0.071073nm,R(F)=5.56%,wR(F2)=14.36%.2적결정학수거위:P2(1)/c,a=0.88968(7)nm,b=1.67562(13)nm,c=0.83666(7)nm,β=115.890(2),V=1.12208(16)nm3,Z=4,Mo Kα,R(F)=4.66%,wR(F2)=10.10%.