东北师大学报(自然科学版)
東北師大學報(自然科學版)
동북사대학보(자연과학판)
JOURNAL OF NORTHEAST NORMAL UNIVERSITY(NATURAL SCIENCE EDITION)
2010年
1期
71-74
,共4页
栾国有%崔立琼%王明辉%吴景贵
欒國有%崔立瓊%王明輝%吳景貴
란국유%최립경%왕명휘%오경귀
超分子%水热合成%晶体结构%多金属氧酸盐
超分子%水熱閤成%晶體結構%多金屬氧痠鹽
초분자%수열합성%정체결구%다금속양산염
super molecular%hydrothermal synthesis%crystal structure%polyoxometalate
利用中温水热技术合成了新型超分子化合物(H_3NCH_2CH_2NH_3)6[P_4Mo_(10)O_(46)]·10H_2O,采用元素分析、红外光谱、热重分析和X射线单晶结构分析对其进行了表征.结果表明:该化合物属于三斜晶系,P-1空间群;晶胞参数 a = 1.089 2 nm,b = 1.583 4 nm,c = 1.997 4 nm,α = 88.523°,β = 78.513°,γ = 71.453°,V = 3.197 8 nm~3,Z = 2,R_1 = 0.031 2,wR_2 = 0.079 5.
利用中溫水熱技術閤成瞭新型超分子化閤物(H_3NCH_2CH_2NH_3)6[P_4Mo_(10)O_(46)]·10H_2O,採用元素分析、紅外光譜、熱重分析和X射線單晶結構分析對其進行瞭錶徵.結果錶明:該化閤物屬于三斜晶繫,P-1空間群;晶胞參數 a = 1.089 2 nm,b = 1.583 4 nm,c = 1.997 4 nm,α = 88.523°,β = 78.513°,γ = 71.453°,V = 3.197 8 nm~3,Z = 2,R_1 = 0.031 2,wR_2 = 0.079 5.
이용중온수열기술합성료신형초분자화합물(H_3NCH_2CH_2NH_3)6[P_4Mo_(10)O_(46)]·10H_2O,채용원소분석、홍외광보、열중분석화X사선단정결구분석대기진행료표정.결과표명:해화합물속우삼사정계,P-1공간군;정포삼수 a = 1.089 2 nm,b = 1.583 4 nm,c = 1.997 4 nm,α = 88.523°,β = 78.513°,γ = 71.453°,V = 3.197 8 nm~3,Z = 2,R_1 = 0.031 2,wR_2 = 0.079 5.
A super molecular compound,(H_3NCH_2CH_2NH_3)6[P_4Mo_(10)O_(46)] 10H_2O,was first prepared by hydrothermal synthesis and characterized by elemental analysis,IR,TGA-DSC and single crystal X-raydiffraction.Crystal data:triclinic,space group P-1,a = 1.089 2 nm,b = 1.583 4 nm,c = 1.997 4 nm,α = 88.523°,β = 78.513°,γ = 71.453°,V = 3.197 8 nm~3,Z = 2,R_1 = 0.031 2,wR_2 = 0.079 5.