CAJ | 학술논문

以丙二酸二乙酯、间苯二酚和1,1,3-三氯丙烯等为原料,经取代、环合、缩合等反应合成了9个含有香豆素基团的二氯丙烯类衍生物,化合物结构经IR、~1H NMR、 MS及元素分析确证.初步的生物活性测定结果表明,该类化合物在400 mg/L质量浓度下对小菜蛾Plutella xylostella有较好的杀虫活性,其中化合物5e对小菜蛾的致死率达到93%.
이병이산이을지、간분이분화1,1,3-삼록병희등위원료,경취대、배합、축합등반응합성료9개함유향두소기단적이록병희류연생물,화합물결구경IR、~1H NMR、 MS급원소분석학증.초보적생물활성측정결과표명,해류화합물재400 mg/L질량농도하대소채아Plutella xylostella유교호적살충활성,기중화합물5e대소채아적치사솔체도93%.
Nine dichloropropene derivatives containing coumarin group were synthesized using diethyl malonate,resorcinol and 1,1,3-trichloropropylene as starting materials via substitution,cyclization and condensation.The structures of the compounds were confirmed by IR,~1H NMR,MS and element analysis.The preliminary bioassay results showed that the title compounds exhibited good insecticidal activity against Plutella xylostella at the concentration of 400 mg/L,the inhibition rate of the compound 5e was 93%.