CAJ | 학술논문

合成了4-硝基邻苯二硫酚配体及相应金属镍配合物,(Bu4N)2[M(nbdt)2](1)和(Bu4N)[M(nbdt)2](2)(nbdt=4-硝基邻苯二硫酚阴离子),并通过X-射线单晶结构测定、循环伏安、ESR谱、紫外可见吸收光谱和变温磁化率实验对其结构和性质进行了表征.这两个化合物均为略有变形的平面四方型配合物.配合物2是由配合物1通过I2氧化制备.配合物2含有一个未成对电子,磁性研究表明由于分子间的自旋耦合使它表现为反铁磁性.
합성료4-초기린분이류분배체급상응금속얼배합물,(Bu4N)2[M(nbdt)2](1)화(Bu4N)[M(nbdt)2](2)(nbdt=4-초기린분이류분음리자),병통과X-사선단정결구측정、순배복안、ESR보、자외가견흡수광보화변온자화솔실험대기결구화성질진행료표정.저량개화합물균위략유변형적평면사방형배합물.배합물2시유배합물1통과I2양화제비.배합물2함유일개미성대전자,자성연구표명유우분자간적자선우합사타표현위반철자성.
Two new nickel complexes with a new 1,2-dithiolate ligand, (Bu4N)2[Ni(nbdt)2] (1) and (Bu4N)[Ni(nbdt)2](2) (nbdt=4-nitro-benzene-1,2-dithiolate), have been synthesized and characterized by X-ray single-crystal structure determination, cyclic voltammetry, ESR, UV/Vis spectra and magnetic susceptibility measurements. Complex 2 was obtained by oxidation of complex 1 with I2. The crystal structure determination reveals that the central Ni atoms in complexes 1 and 2 are in slightly distorted square-planar coordination environment. The cyclic voltammetric studies show that there are two oxidation peaks at 0.15 and 0.85 V for complex 1. The antiferromagnetic interaction dominates the magnetic properties in complex 2. CCDC: 287714; 287715.