化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2010年
2期
171-175
,共5页
谭义秋%黄祖强%农克良%周树年
譚義鞦%黃祖彊%農剋良%週樹年
담의추%황조강%농극량%주수년
机械活化%羧甲基淀粉%Cu~(2+)%吸附
機械活化%羧甲基澱粉%Cu~(2+)%吸附
궤계활화%최갑기정분%Cu~(2+)%흡부
mechanical activation%earboxymethyl starch%Cu~(2+)%adsorption
采用搅拌球磨机对木薯淀粉进行机械活化,以活化60 min的木薯淀粉为原料,干法合成羧甲基淀粉吸附剂.考察羧甲基淀粉的取代度、溶液的pH值、Cu~(2+)的初始浓度、吸附时间、羧甲基淀粉的投加量等因素对羧甲基淀粉吸附Cu~(2+)性能的影响.结果表明,该羧甲基淀粉对Cu~(2+)有很好的吸附作用;用取代度为0.841的羧甲基淀粉处理含Cu~(2+)的废水,在pH=7.0、羧甲基淀粉的投加量50.00 mg/L、吸附时间15 min时,羧甲基淀粉对废水中Cu~(2+)的吸附率高达98.80%,处理后的水质达到国家污水综合排放标准(GB8978-1996)中一级标准要求.
採用攪拌毬磨機對木藷澱粉進行機械活化,以活化60 min的木藷澱粉為原料,榦法閤成羧甲基澱粉吸附劑.攷察羧甲基澱粉的取代度、溶液的pH值、Cu~(2+)的初始濃度、吸附時間、羧甲基澱粉的投加量等因素對羧甲基澱粉吸附Cu~(2+)性能的影響.結果錶明,該羧甲基澱粉對Cu~(2+)有很好的吸附作用;用取代度為0.841的羧甲基澱粉處理含Cu~(2+)的廢水,在pH=7.0、羧甲基澱粉的投加量50.00 mg/L、吸附時間15 min時,羧甲基澱粉對廢水中Cu~(2+)的吸附率高達98.80%,處理後的水質達到國傢汙水綜閤排放標準(GB8978-1996)中一級標準要求.
채용교반구마궤대목서정분진행궤계활화,이활화60 min적목서정분위원료,간법합성최갑기정분흡부제.고찰최갑기정분적취대도、용액적pH치、Cu~(2+)적초시농도、흡부시간、최갑기정분적투가량등인소대최갑기정분흡부Cu~(2+)성능적영향.결과표명,해최갑기정분대Cu~(2+)유흔호적흡부작용;용취대도위0.841적최갑기정분처리함Cu~(2+)적폐수,재pH=7.0、최갑기정분적투가량50.00 mg/L、흡부시간15 min시,최갑기정분대폐수중Cu~(2+)적흡부솔고체98.80%,처리후적수질체도국가오수종합배방표준(GB8978-1996)중일급표준요구.
The carboxymethyl starch(CMS)adsorbent was prepared by dry method using the cassava starch,mechanically activated for 60 min by a stirring-type ball mill,as a starting material.The effects of degree of substitution(DS) of carboxymethyl starch,solution pH value,Cu~(2+) initial concentration,adsorption time,and the dosage of carboxymethyl starch to the adsorption abilities of the adsorbent on Cu~(2+) were investigated.The results indicated that the adsorption abilities of the carboxymethyl starch on Cu~(2+) were better.Treated waste water of containing Cu~(2+) by the carboxymethyl starch,the adsorption rate of Cu~(2+) reached 98.80%,when the dosage of the carboxymethyl starch(DS=0.841)50.00mg/L,pH value equal to 7.0,the adsorption time 15 min.The effluent water could reach the national first class discharge standards(GB8978-1996).