天然产物研究与开发
天然產物研究與開髮
천연산물연구여개발
NATURAL PRODUCT RESEARCH AND DEVELOPMENT
2012年
1期
69-75,93
,共8页
曾映旭%赵晨曦%王小梅%吴天泉%刘琳琪%梁逸曾
曾映旭%趙晨晞%王小梅%吳天泉%劉琳琪%樑逸曾
증영욱%조신희%왕소매%오천천%류림기%량일증
植物籽油%脂肪酸%气相色谱-质谱法%衍生化
植物籽油%脂肪痠%氣相色譜-質譜法%衍生化
식물자유%지방산%기상색보-질보법%연생화
plant seed oil%fatty acid%gas chromatography-mass spectrometry%derivatization
为寻求新的食用油资源,发展了一种快速可靠的气相色谱-质谱联用方法,用于植物籽油中脂肪酸成分的定性鉴定和含量测定.所建立的方法成功用于葡萄籽、南瓜籽和猕猴桃籽等七种植物籽油中的棕榈酸、十八烷酸、油酸、亚油酸和α-亚麻酸的定性定量分析.结果表明,刺葡萄籽油、普通葡萄籽油、国外葡萄籽油、南瓜籽油、枸杞籽油和西番莲籽油均具有相似的脂肪酸谱,尽管其中它们所含上述五种脂肪酸含量不同,由于均存在人体所必需的饱和与不饱和脂肪酸,故可以用作替代食用油.猕猴桃籽油因为其存在高含量的α-亚麻酸成分,可能是更好的食用油和营养油资源.本文首次对枸杞籽油、西番莲籽油和猕猴桃籽油脂肪酸成分进行绝对含量分析,为新的食用油资源的开发提供了重要的依据.
為尋求新的食用油資源,髮展瞭一種快速可靠的氣相色譜-質譜聯用方法,用于植物籽油中脂肪痠成分的定性鑒定和含量測定.所建立的方法成功用于葡萄籽、南瓜籽和獼猴桃籽等七種植物籽油中的棕櫚痠、十八烷痠、油痠、亞油痠和α-亞痳痠的定性定量分析.結果錶明,刺葡萄籽油、普通葡萄籽油、國外葡萄籽油、南瓜籽油、枸杞籽油和西番蓮籽油均具有相似的脂肪痠譜,儘管其中它們所含上述五種脂肪痠含量不同,由于均存在人體所必需的飽和與不飽和脂肪痠,故可以用作替代食用油.獼猴桃籽油因為其存在高含量的α-亞痳痠成分,可能是更好的食用油和營養油資源.本文首次對枸杞籽油、西番蓮籽油和獼猴桃籽油脂肪痠成分進行絕對含量分析,為新的食用油資源的開髮提供瞭重要的依據.
위심구신적식용유자원,발전료일충쾌속가고적기상색보-질보련용방법,용우식물자유중지방산성분적정성감정화함량측정.소건립적방법성공용우포도자、남과자화미후도자등칠충식물자유중적종려산、십팔완산、유산、아유산화α-아마산적정성정량분석.결과표명,자포도자유、보통포도자유、국외포도자유、남과자유、구기자유화서번련자유균구유상사적지방산보,진관기중타문소함상술오충지방산함량불동,유우균존재인체소필수적포화여불포화지방산,고가이용작체대식용유.미후도자유인위기존재고함량적α-아마산성분,가능시경호적식용유화영양유자원.본문수차대구기자유、서번련자유화미후도자유지방산성분진행절대함량분석,위신적식용유자원적개발제공료중요적의거.
To find new edible oil sources,a rapid and reliable gas chromatography mass spe.ctrometry method for fatty acid identification and quantitation was developed.The proposed method was then used to quantitation of palmitic acid,stearic acid,oleic acid,linoleic acid and α-linolenic acid in seven different plant seend oils.The fatty acid profiles of spine grape seed,grape seed,foreign grape seed,pumpkin seed,barbary wolfberry fruit seed and passion flower seed oils are similar with different contents of the five fatty acids,indicating they can be alternative sources of edible oil due to the presence of all saturated and unsaturated fatty acids required for human health.Yangtao kiwifruit seed oil may be much better alternative source of edible and nutritional oil because of a high content of α-linolenic acid.This is the first research on the absolute content analysis of fatty acid composition of barbary wolfberry fruit seed oil,passion flower seed oil and yangtao kiwifruit seed oil which provides an important and scientific basis for new edible oil resource exploitation.