化学通报(印刷版)
化學通報(印刷版)
화학통보(인쇄판)
CHEMISTRY
2009年
12期
1122-1128
,共7页
朱丽%王一平%张志英%黄群武%张妍
硃麗%王一平%張誌英%黃群武%張妍
주려%왕일평%장지영%황군무%장연
聚光光伏%冷却%耐受性%丙三醇
聚光光伏%冷卻%耐受性%丙三醇
취광광복%냉각%내수성%병삼순
Concentration photovohaic%Cooling%Weather-resistance%Glycerol
设计了高温、紫外及温度紫外耦合实验考察丙三醇的耐候性.利用紫外可见光谱仪、红外光谱仪检测实验前后丙i醇性质的变化,并测试了液浸硅电池的电性能和表面形貌的变化.结果表明,实验后丙三醇的光谱透过率在小于600nm的低波段有所降低,红外光谱显示其发生了氧化反应生成微最的羰基.用丙三醇液浸硅电池的电性能没有衰降,但是电池表面出现了微量颗粒状物质.用理论分析了液体性质变化的原因,并由此建议醇类液体不适于在液浸光伏系统中作为冷却液体.
設計瞭高溫、紫外及溫度紫外耦閤實驗攷察丙三醇的耐候性.利用紫外可見光譜儀、紅外光譜儀檢測實驗前後丙i醇性質的變化,併測試瞭液浸硅電池的電性能和錶麵形貌的變化.結果錶明,實驗後丙三醇的光譜透過率在小于600nm的低波段有所降低,紅外光譜顯示其髮生瞭氧化反應生成微最的羰基.用丙三醇液浸硅電池的電性能沒有衰降,但是電池錶麵齣現瞭微量顆粒狀物質.用理論分析瞭液體性質變化的原因,併由此建議醇類液體不適于在液浸光伏繫統中作為冷卻液體.
설계료고온、자외급온도자외우합실험고찰병삼순적내후성.이용자외가견광보의、홍외광보의검측실험전후병i순성질적변화,병측시료액침규전지적전성능화표면형모적변화.결과표명,실험후병삼순적광보투과솔재소우600nm적저파단유소강저,홍외광보현시기발생료양화반응생성미최적탄기.용병삼순액침규전지적전성능몰유쇠강,단시전지표면출현료미량과립상물질.용이론분석료액체성질변화적원인,병유차건의순류액체불괄우재액침광복계통중작위냉각액체.
In order to efficient cooling in CPV system, Glycerol was used in this paper for cooling solar cells by direct immersing the cells in it. High temperature tests (85℃ and 150℃ ), UV-light test and high temperature and UV coupling test were designed for investigating the weather-resistance of glycerol. The changes of glycerol after tests were measured by UV-Vis and FT-IR spectra, also the Voc, Isc and the surface of the immersing cells were measured before and after tests.The results indicated that the transmittance began to decrease at about 600nm and trace of carbonyl was produced by oxidation reaction in glycerol. No electrical degradation in immersed Si cells was investigated and only minim substance of varied shape and size appeared on the surface of cells. It is advised that alcohols liquid is unsuitable as cooling liquid in liquid-immersing CPV system based on the analysis of the phenomena.