CAJ | 학술논문

利用紫外可见吸收光谱法考察了八元瓜环与金橙G和亚甲基蓝的相互作用情况。考察了溶液的酸度对作用体系的影响。结果表明,八元瓜环与客体的相互作用随客体及溶液pH的不同而有所改变。在pH=1～12的范围内,八元瓜环与金橙G作用明显,形成稳定的2：1的主客体包结配合物;而八元瓜环与亚甲基蓝（g4）的相互作用则在pH=1～10的范围内形成2：3的包结配合物,当pH〉13后,则趋向于形成1：2的包结配合物,且随着pH值的增加,溶液颜色由蓝变紫。
이용자외가견흡수광보법고찰료팔원과배여금등G화아갑기람적상호작용정황。고찰료용액적산도대작용체계적영향。결과표명,팔원과배여객체적상호작용수객체급용액pH적불동이유소개변。재pH=1～12적범위내,팔원과배여금등G작용명현,형성은정적2：1적주객체포결배합물;이팔원과배여아갑기람（g4）적상호작용칙재pH=1～10적범위내형성2：3적포결배합물,당pH〉13후,칙추향우형성1：2적포결배합물,차수착pH치적증가,용액안색유람변자。
Interaction between Q[8] with Orange G and methylene blue were investigated by using ultraviolet-visible absorption spectrophotometry.The influence of pH on the interaction were studied in detail.The results showed that the stability of the inclusion complexes was related to the guests and the pH of solution.Q[8] can interact with guest of g1 completely with a ratio of 2：1 at pH=1～12,and Q[8] can interact with guest of g4 completely with a ratio of 2：3 at pH=1～10.However,the inclusion complexes of Q[8] and g4 completely with a ratio of 1：2 at pH13,and with the decrease of acidity,the color of the solution changed from blue to purple.