沈阳化工大学学报
瀋暘化工大學學報
침양화공대학학보
JOURNAL OF SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
2011年
3期
250-255
,共6页
水滑石%共沉淀法%阻燃剂
水滑石%共沉澱法%阻燃劑
수활석%공침정법%조연제
LDHs%coprecipitation method%fire-retardant
将具有润滑功能的锌元素引入到镁铝型水滑石的主体层板化学组成中.通过实验研究Mg-Al水滑石、Zn-Al水滑石和Zn-Mg-Al水滑石合成及它们对软PVC阻燃性能和力学性能的影响.实验结果表明:在相同的添加量(20份)情况下,添加水滑石阻燃剂的PVC力学性能与添加Al(OH)3和Mg(OH)2差别不大.然而,水滑石的阻燃性能明显优于传统阻燃剂Al(OH)3和Mg(OH)2.Zn-Mg-Al水滑石表现出比Mg-Al水滑石和Zn-Al水滑石更好的阻燃性能.
將具有潤滑功能的鋅元素引入到鎂鋁型水滑石的主體層闆化學組成中.通過實驗研究Mg-Al水滑石、Zn-Al水滑石和Zn-Mg-Al水滑石閤成及它們對軟PVC阻燃性能和力學性能的影響.實驗結果錶明:在相同的添加量(20份)情況下,添加水滑石阻燃劑的PVC力學性能與添加Al(OH)3和Mg(OH)2差彆不大.然而,水滑石的阻燃性能明顯優于傳統阻燃劑Al(OH)3和Mg(OH)2.Zn-Mg-Al水滑石錶現齣比Mg-Al水滑石和Zn-Al水滑石更好的阻燃性能.
장구유윤활공능적자원소인입도미려형수활석적주체층판화학조성중.통과실험연구Mg-Al수활석、Zn-Al수활석화Zn-Mg-Al수활석합성급타문대연PVC조연성능화역학성능적영향.실험결과표명:재상동적첨가량(20빈)정황하,첨가수활석조연제적PVC역학성능여첨가Al(OH)3화Mg(OH)2차별불대.연이,수활석적조연성능명현우우전통조연제Al(OH)3화Mg(OH)2.Zn-Mg-Al수활석표현출비Mg-Al수활석화Zn-Al수활석경호적조연성능.
Lubricated zinc was introduced into the chemical composition of the main laminate of the Mg-Al hydrotalcite.The chemosynthesis of Mg-Al hydrotalcite,Zn-Al hydrotalcite and Zn-Mg-Al hydrotalcite were investigated and as flame-retardants for flexible poly(vinyl chilride) they were studied by thermal analysis test and LOI test.The results show that,Mg-Al-CO3 LDHs,Zn-Al-CO3 LDHs,Zn-Mg-Al-CO3 LDHs can improve the thermal stability of soft PVC.Under the same conditions,the flame retardant properties of hydrotalcite was better than Al(OH)3 and Mg(OH)2.In the same dosage(20 phr) case,zinc-based ternary Mg-Al Hydrotalcite-like performance was better than the Mg-Al hydrotalcite and Zn-Al hydrotalcite for flame retardancy.