能源研究与管理
能源研究與管理
능원연구여관리
JIANGXI ENERGY
2011年
3期
20-22
,共3页
张玉梅%曹菊琴%刘建平%张逢源
張玉梅%曹菊琴%劉建平%張逢源
장옥매%조국금%류건평%장봉원
水溶性导电聚苯胺%电化学活性%稳定性
水溶性導電聚苯胺%電化學活性%穩定性
수용성도전취분알%전화학활성%은정성
conductive polyaniline aqueous dispersion%electroactvity%stability
以含短链亲水基团的酸性磷酸酯为掺杂剂合成新型导电聚苯胺纳米水分散液，通过透射电子显微镜、循环伏安法对其形貌和电化学性能进行表征。研究表明：合成的聚苯胺为直径20-80nm且均匀分散的球状粒子；分散液在碱性介质中仍保持较好的电化学活性及稳定性。该研究为水溶性导电聚苯胺在抗腐蚀等碱性环境中的应用提供了更广阔的思路。
以含短鏈親水基糰的痠性燐痠酯為摻雜劑閤成新型導電聚苯胺納米水分散液，通過透射電子顯微鏡、循環伏安法對其形貌和電化學性能進行錶徵。研究錶明：閤成的聚苯胺為直徑20-80nm且均勻分散的毬狀粒子；分散液在堿性介質中仍保持較好的電化學活性及穩定性。該研究為水溶性導電聚苯胺在抗腐蝕等堿性環境中的應用提供瞭更廣闊的思路。
이함단련친수기단적산성린산지위참잡제합성신형도전취분알납미수분산액，통과투사전자현미경、순배복안법대기형모화전화학성능진행표정。연구표명：합성적취분알위직경20-80nm차균균분산적구상입자；분산액재감성개질중잉보지교호적전화학활성급은정성。해연구위수용성도전취분알재항부식등감성배경중적응용제공료경엄활적사로。
Nanoscale conductive polyaniline aqueous dispersion was prepared by acidic phosphate ester with a short hydrophilic unit as a dopant and characterized by Transmission Electron Microscope and Cylic Voltammograms. The results showed that spherical particles of polyaniline were distributed uniformly and the size ranged from 20 nm to 80 nm. In addition, electrochemical activity of the conductive polymer dispersion was still kept in alkaline media and it displayed an excellent stability upon cycling. The investigation broadens fields of prospective application of conductive polyaniline in alkaline solution such as anticorrosion.
