化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2010年
3期
478-483,489
,共7页
氢转移反应%反应条件%催化剂%氢供体%反应类型
氫轉移反應%反應條件%催化劑%氫供體%反應類型
경전이반응%반응조건%최화제%경공체%반응류형
hydrogen transfer reaction%reaction condition%catalyst%hydrogen donor%reaction type
氢转移反应是利用氢供体作为氢源对氢受体进行还原的一类反应,该反应与普通的氢气加氢反应相比,反应条件温和、对设备要求不高,在实验室研究和工业生产中均有广阔的应用前景.本文作者在研究氢转移反应还原芳磺酸的基础上,对氢转移反应的工艺条件、催化剂和氢供体种类、适用的反应类型等进行了较系统的总结,重点对近年来的相关文献进行了综述,表明氢转移反应是一种高效、绿色、资源化利用氢供体的氢化、氢解还原工艺.
氫轉移反應是利用氫供體作為氫源對氫受體進行還原的一類反應,該反應與普通的氫氣加氫反應相比,反應條件溫和、對設備要求不高,在實驗室研究和工業生產中均有廣闊的應用前景.本文作者在研究氫轉移反應還原芳磺痠的基礎上,對氫轉移反應的工藝條件、催化劑和氫供體種類、適用的反應類型等進行瞭較繫統的總結,重點對近年來的相關文獻進行瞭綜述,錶明氫轉移反應是一種高效、綠色、資源化利用氫供體的氫化、氫解還原工藝.
경전이반응시이용경공체작위경원대경수체진행환원적일류반응,해반응여보통적경기가경반응상비,반응조건온화、대설비요구불고,재실험실연구화공업생산중균유엄활적응용전경.본문작자재연구경전이반응환원방광산적기출상,대경전이반응적공예조건、최화제화경공체충류、괄용적반응류형등진행료교계통적총결,중점대근년래적상관문헌진행료종술,표명경전이반응시일충고효、록색、자원화이용경공체적경화、경해환원공예.
Hydrogen transfer reaction is a kind of reduction reaction,in which the hydrogen donor is used as hydrogen source.Compared with hydrogenation using hydrogen gas,hydrogen transfer reaction is widely applicable both in laboratory research and industrial production,benefit from its mild reaction condition and low equipment requirement.Based on the hydrogen transfer reaction of aromatic sulfonic acid,related reaction factors are summarized,including reaction condition,catalyst,hydrogen donor and applicable reaction types.Related literatures published after the year of 2000 are mainly reviewed.Hydrogen transfer reaction is indicated to be an efficient and green technology to perform hydrogenation and hydrogenolysis reduction.
