物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2007年
8期
1288-1290
,共3页
贾若琨%和东亮%戴洁%杨文胜%白玉白
賈若琨%和東亮%戴潔%楊文勝%白玉白
가약곤%화동량%대길%양문성%백옥백
上转换%微波制备%Y2O3
上轉換%微波製備%Y2O3
상전환%미파제비%Y2O3
Upconversion%Microwave preparation%Y2O3
采用微波法和溶胶-凝胶法制备了(Y2O3:Er3+)粒子.微波法制备过程中烧结温度降低到600 ℃.980 nm激光激发下得到550和660 nm两个上转换发射带.微波法制备的上转换材料得到了强的红光发射和弱的绿光发射,溶胶-凝胶法制备的材料得到了强的绿色发射和弱的红光发射.结果表明,微波促进了S6对称性的形成,S6对称性促进了红光的发射.
採用微波法和溶膠-凝膠法製備瞭(Y2O3:Er3+)粒子.微波法製備過程中燒結溫度降低到600 ℃.980 nm激光激髮下得到550和660 nm兩箇上轉換髮射帶.微波法製備的上轉換材料得到瞭彊的紅光髮射和弱的綠光髮射,溶膠-凝膠法製備的材料得到瞭彊的綠色髮射和弱的紅光髮射.結果錶明,微波促進瞭S6對稱性的形成,S6對稱性促進瞭紅光的髮射.
채용미파법화용효-응효법제비료(Y2O3:Er3+)입자.미파법제비과정중소결온도강저도600 ℃.980 nm격광격발하득도550화660 nm량개상전환발사대.미파법제비적상전환재료득도료강적홍광발사화약적록광발사,용효-응효법제비적재료득도료강적록색발사화약적홍광발사.결과표명,미파촉진료S6대칭성적형성,S6대칭성촉진료홍광적발사.
Erbium doped Y2O3 (Y2O3:Er3+) particles were prepared by microwave method and sol-gel method. Using microwave method the calcining temperature was decreased to 600 ℃. Two upconverting emission bands centered at 550 and 660 nm were presented under 980 nm laser excitation. Samples prepared by microwave method showed a strong red emission and a week green emission, while samples prepared by sol-gel method showed a strong green emission and a week red emission. The results showed that microwave promoted the formation of S6 symmetric structures and the S6 symmetric structures promoted the red emission.