CAJ | 학술논문

综述了环烯烃加成聚合的催化剂体系及其聚合物的研究和开发状况。主要介绍了催化剂种类，包括传统的齐格勒-纳塔(Ziegler-Natta)催化剂、茂金属催化剂、钯、镍等后过渡金属催化剂，及其催化环烯烃均聚合以及与α-烯烃共聚合的特性。也描述了用不同催化体系进行环烯烃聚合的机理以及环烯烃加成聚合物及其与α-烯烃共聚物的性能及应用前景。
종술료배희경가성취합적최화제체계급기취합물적연구화개발상황。주요개소료최화제충류，포괄전통적제격륵-납탑(Ziegler-Natta)최화제、무금속최화제、파、얼등후과도금속최화제，급기최화배희경균취합이급여α-희경공취합적특성。야묘술료용불동최화체계진행배희경취합적궤리이급배희경가성취합물급기여α-희경공취물적성능급응용전경。
The research and development of addition polymerization ofcycloolefins and the properties of polycycloolefins are reviewed.This paper mainly describes the typies of the catalysts,including typical Ziegler-Natta catalysts,metallocene catalysts and posttransition metals such as Pd and Ni complexes,and their catalyzing specificity for the cycloolefins homopolymerization and copolymerization with α-olefins.Mechanism o f the polymerization with different catalysts and properties and applications of the cycloolefin polymers and the cycloolefin-α-olefin copolymers are also introduced.