物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2000年
3期
202-206
,共5页
胡瑞省%刘善堂%朱梓华%朱涛%刘忠范
鬍瑞省%劉善堂%硃梓華%硃濤%劉忠範
호서성%류선당%주재화%주도%류충범
金纳米粒子%硅烷化%组装
金納米粒子%硅烷化%組裝
금납미입자%규완화%조장
Gold nanoparticles%Silanization%Assembly
采用水相硅烷化方法,将3氨基丙基三甲氧基硅烷(APS)组装在湿化学法处理的单晶硅表面上.接触角、原子力显微镜(AFM)、X射线光电子能谱(XPS)表征结果显示得到了平整均匀的具有氨基表面的自组装膜.SEM观察表明,16nm的金纳米粒子可以在上述氨基表面上形成均匀的亚单层排布,得到具有Au纳米粒子/APS/Si形式的纳米复合结构,进一步的处理可以使金纳米粒子在表面上的排列由随机趋于有序化.
採用水相硅烷化方法,將3氨基丙基三甲氧基硅烷(APS)組裝在濕化學法處理的單晶硅錶麵上.接觸角、原子力顯微鏡(AFM)、X射線光電子能譜(XPS)錶徵結果顯示得到瞭平整均勻的具有氨基錶麵的自組裝膜.SEM觀察錶明,16nm的金納米粒子可以在上述氨基錶麵上形成均勻的亞單層排佈,得到具有Au納米粒子/APS/Si形式的納米複閤結構,進一步的處理可以使金納米粒子在錶麵上的排列由隨機趨于有序化.
채용수상규완화방법,장3안기병기삼갑양기규완(APS)조장재습화학법처리적단정규표면상.접촉각、원자력현미경(AFM)、X사선광전자능보(XPS)표정결과현시득도료평정균균적구유안기표면적자조장막.SEM관찰표명,16nm적금납미입자가이재상술안기표면상형성균균적아단층배포,득도구유Au납미입자/APS/Si형식적납미복합결구,진일보적처리가이사금납미입자재표면상적배렬유수궤추우유서화.
Chemically-wet treated silicon substrate was modified with self-assembled monolayer of 3-aminopropyl-trimethylsilane by aqueous phase silanization,giving an ultrasmooth and homogenous surface terminated with amino groups.Colloidal gold nanoparticles (15.7± 2.0 nm)were adsorbed on such a surface with a submonolayer coverage and a random particle distribution.Increases in local surface coverage and packing order were induced by capping the assembled gold nanoparticles with alkanthiol molecules in an enthanolic solution.