CAJ | 학술논문

研究了一种利用无荧光稀土配合物与同一受体材料形成的界面激基复合物的发射来大致估算其最低未占据轨道(LUMO)能级简单方法.镥、钆、钪三种稀土配合物与星形爆炸物形成的激基复合物发射峰位分别在590,607和656 nm,与此相对应LUMO能级计算结果大致为3.0,3.06,3.21 eV.
연구료일충이용무형광희토배합물여동일수체재료형성적계면격기복합물적발사래대치고산기최저미점거궤도(LUMO)능급간단방법.노、구、항삼충희토배합물여성형폭작물형성적격기복합물발사봉위분별재590,607화656 nm,여차상대응LUMO능급계산결과대치위3.0,3.06,3.21 eV.
A simple method for approximately accounting the lowest unoccupied molecular orbital (LUMO) level of RE-complexes from their exciplex emissions with low ionization potential hole transfer material, 4,4′,4″-tris[3-methyl-pheny(phenyl)amino]triphenylamine (m-MTDATA) was investigated. The EL emission peaks located at 590,607,and 656 nm, and the LUMO levels of the RE-complexes approximately were calculated to be about 3.0, 3.06 and 3.21 eV for the Lu-, Gd- and Sc-complexes, respectively.