石油与天然气化工
石油與天然氣化工
석유여천연기화공
CHEMICAL ENGINEERING OF OIL AND GAS
2010年
2期
101-103,118
,共4页
单层分散%氨吸附%氯化锶
單層分散%氨吸附%氯化鍶
단층분산%안흡부%록화송
monolayer dispersion%ammonia adsorption%SrCl2
本文以单层分散理论为指导,制备了SrCl2/SiO2吸附剂.对制备的样品进行XRD检测和氨吸附性能测试,研究了焙烧温度和担载量对氯化锶在粗孔硅胶载体上单层分散效果和吸附特性的影响.研究结果表明:氯化锶在粗孔硅胶载体上分散的适宜焙烧温度为500℃,其分散阈值小于0.3 g/g;氯化锶在粗孔硅胶载体上的分散状况不同,其吸附特征也不同;单层分散效果好的吸附剂具有非常良好的吸附稳定性.
本文以單層分散理論為指導,製備瞭SrCl2/SiO2吸附劑.對製備的樣品進行XRD檢測和氨吸附性能測試,研究瞭焙燒溫度和擔載量對氯化鍶在粗孔硅膠載體上單層分散效果和吸附特性的影響.研究結果錶明:氯化鍶在粗孔硅膠載體上分散的適宜焙燒溫度為500℃,其分散閾值小于0.3 g/g;氯化鍶在粗孔硅膠載體上的分散狀況不同,其吸附特徵也不同;單層分散效果好的吸附劑具有非常良好的吸附穩定性.
본문이단층분산이론위지도,제비료SrCl2/SiO2흡부제.대제비적양품진행XRD검측화안흡부성능측시,연구료배소온도화담재량대록화송재조공규효재체상단층분산효과화흡부특성적영향.연구결과표명:록화송재조공규효재체상분산적괄의배소온도위500℃,기분산역치소우0.3 g/g;록화송재조공규효재체상적분산상황불동,기흡부특정야불동;단층분산효과호적흡부제구유비상량호적흡부은정성.
On the basis of theory of "Spontaneous Monolayer Dispersion of Oxides and Salts onto Surface of Supports", the effects of different calcination temperatures, load capacities on the monolayer dispersion of SrCl2 onto silica gel were studied by XRD, and the ammonia adsorption of samples was measured. It indicates that it is optimal to calcine samples at 500℃ for the monolayer dispersion of SrCl2onto silica gel, and the monolayer dispersion threshold is lower than 0. 3g/g. Ammonia adsorption capacity of the sample calcined at 500℃ is the strongest in the different calcination temperatures. Ammonia pressure has different effects on ammonia adsorption capacity to different load samples.