林业科学
林業科學
임업과학
SCIENTIA SILVAE SINICAE
2007年
8期
106-110
,共5页
孙芳利%段新芳%毛胜凤%吕建全%王建辉
孫芳利%段新芳%毛勝鳳%呂建全%王建輝
손방리%단신방%모성봉%려건전%왕건휘
竹材%壳聚糖金属配合物%耐腐性能%力学强度%胶接强度
竹材%殼聚糖金屬配閤物%耐腐性能%力學彊度%膠接彊度
죽재%각취당금속배합물%내부성능%역학강도%효접강도
bamboo wood%chitosan metal complex%decay-resistance%mechanical strength%gluing performance
以4年生新伐毛竹为试材,以褐腐菌棉腐卧孔菌为试菌,对壳聚糖铜配合物(CCC)、壳聚糖锌配合物(CZC)及相应的金属盐(氯化锌)和铜铬硼(CCB)、ACQ处理材的耐腐性能、力学性能及胶接性能进行研究.结果表明:1) CCC处理的竹材对棉腐卧孔菌的耐腐性能不及CCB和ACQ处理材;但是,随着CCC处理浓度的增加,处理材耐褐腐性能明显增加,当处理材中金属离子保持量达到5.141 kg·m-3时,腐朽后质量损失低于6.1%.2) CZC处理毛竹试材的耐腐效果低于CCC、CCB和ACQ,略高于氯化锌处理材,当CZC中金属离子保持量高于5.091 kg·m-3时,处理材的质量损失在26.4%~29.0%之间.3) 同素材(未处理材)相比,经防腐剂处理后的竹材力学性能及胶接性能均有不同程度下降,尤其是CCB处理材.在所测指标中,抗弯弹性模量和抗弯强度下降最明显,横纹抗压强度和胶接强度除CCB外变化不大.
以4年生新伐毛竹為試材,以褐腐菌棉腐臥孔菌為試菌,對殼聚糖銅配閤物(CCC)、殼聚糖鋅配閤物(CZC)及相應的金屬鹽(氯化鋅)和銅鉻硼(CCB)、ACQ處理材的耐腐性能、力學性能及膠接性能進行研究.結果錶明:1) CCC處理的竹材對棉腐臥孔菌的耐腐性能不及CCB和ACQ處理材;但是,隨著CCC處理濃度的增加,處理材耐褐腐性能明顯增加,噹處理材中金屬離子保持量達到5.141 kg·m-3時,腐朽後質量損失低于6.1%.2) CZC處理毛竹試材的耐腐效果低于CCC、CCB和ACQ,略高于氯化鋅處理材,噹CZC中金屬離子保持量高于5.091 kg·m-3時,處理材的質量損失在26.4%~29.0%之間.3) 同素材(未處理材)相比,經防腐劑處理後的竹材力學性能及膠接性能均有不同程度下降,尤其是CCB處理材.在所測指標中,抗彎彈性模量和抗彎彊度下降最明顯,橫紋抗壓彊度和膠接彊度除CCB外變化不大.
이4년생신벌모죽위시재,이갈부균면부와공균위시균,대각취당동배합물(CCC)、각취당자배합물(CZC)급상응적금속염(록화자)화동락붕(CCB)、ACQ처리재적내부성능、역학성능급효접성능진행연구.결과표명:1) CCC처리적죽재대면부와공균적내부성능불급CCB화ACQ처리재;단시,수착CCC처리농도적증가,처리재내갈부성능명현증가,당처리재중금속리자보지량체도5.141 kg·m-3시,부후후질량손실저우6.1%.2) CZC처리모죽시재적내부효과저우CCC、CCB화ACQ,략고우록화자처리재,당CZC중금속리자보지량고우5.091 kg·m-3시,처리재적질량손실재26.4%~29.0%지간.3) 동소재(미처리재)상비,경방부제처리후적죽재역학성능급효접성능균유불동정도하강,우기시CCB처리재.재소측지표중,항만탄성모량화항만강도하강최명현,횡문항압강도화효접강도제CCB외변화불대.
The mechanical strength, gluing performance and decay-resistance of 4-year-old bamboo wood treated with chitosan copper/zinc complexes (CCC and CZC),CCB(copper, chromium, boron composites),ACQ and zinc chloride were reported in this paper. Results showed as follows: 1) The decay resistance of CCC against Poria placenta was inferior to CCB and ACQ. But the ability of resisting yellow-rot fungi increased greatly with the increase of CCC concentration. When the metal ion retention in bamboo wood reached 5.141 kg·m-3, mass loss of the treated bamboo wood was below 6.1%. 2) The decay resistance of CZC against Poria placenta was evidently lower than that of CCC,CCB and ACQ , but slightly better than that of zinc chloride. When the metal ion retention in bamboo wood exceeded 5.091 kg·m-3, mass losses of the treated bamboo wood were between 26.4% and 29.0%. 3) The mechanical strength and gluing performance dropped at different degrees, especially for CCB preservative. Among the experimental indexes, the values of bending modulus and bending strength decreased the most, while the compression strength vertical to grain and the gluing strength had nearly no changes except for CCB.