稀有金属材料与工程
稀有金屬材料與工程
희유금속재료여공정
RARE METAL MATERIALS AND ENGINEERNG
2009年
z2期
624-626
,共3页
傅向军%廖家轩%张佳%潘笑风%王洪全%魏雄邦
傅嚮軍%廖傢軒%張佳%潘笑風%王洪全%魏雄邦
부향군%료가헌%장가%반소풍%왕홍전%위웅방
铈掺杂%钛酸锶钡薄膜%钙钛矿结构%介电性能
鈰摻雜%鈦痠鍶鋇薄膜%鈣鈦礦結構%介電性能
시참잡%태산송패박막%개태광결구%개전성능
cerium doping%barium strontium titanate film%perovskited structure%dielectric properties
用改善的溶胶凝胶法制备铈掺杂钛酸锶钡(Ba_0.6Sr_0.4TiO_3, BST)薄膜,研究其结构与介电性能.X射线光电子能谱表明,铈掺杂显著地减少了薄膜表面非钙钛矿结构.但是,由于掺杂薄膜较薄且掺杂量小,X射线衍射结果未见明显变化.原子力显微镜结果表明,掺杂BST薄膜表面光滑致密.掺杂BST薄膜的介电性能大幅度提高,在40 V外加电压下介电调谐率达60.8%,零偏压下的介电损耗为0.0265.同时,就有关结构及介电性能改善的机制进行了讨论.
用改善的溶膠凝膠法製備鈰摻雜鈦痠鍶鋇(Ba_0.6Sr_0.4TiO_3, BST)薄膜,研究其結構與介電性能.X射線光電子能譜錶明,鈰摻雜顯著地減少瞭薄膜錶麵非鈣鈦礦結構.但是,由于摻雜薄膜較薄且摻雜量小,X射線衍射結果未見明顯變化.原子力顯微鏡結果錶明,摻雜BST薄膜錶麵光滑緻密.摻雜BST薄膜的介電性能大幅度提高,在40 V外加電壓下介電調諧率達60.8%,零偏壓下的介電損耗為0.0265.同時,就有關結構及介電性能改善的機製進行瞭討論.
용개선적용효응효법제비시참잡태산송패(Ba_0.6Sr_0.4TiO_3, BST)박막,연구기결구여개전성능.X사선광전자능보표명,시참잡현저지감소료박막표면비개태광결구.단시,유우참잡박막교박차참잡량소,X사선연사결과미견명현변화.원자력현미경결과표명,참잡BST박막표면광활치밀.참잡BST박막적개전성능대폭도제고,재40 V외가전압하개전조해솔체60.8%,령편압하적개전손모위0.0265.동시,취유관결구급개전성능개선적궤제진행료토론.
Cerium (Ce)-doped barium strontium titanate (Ba0.6Sr0.4TiO3, BST) films were prepared by improved Sol-gel method. The structure and dielectric properties of the films were studied. X-ray diffraction shows the Ce-doped BST films exhibit no obvious change in phase structure because the films are quite thin and the doping content of Ce is low. However X-ray photoelectron spectroscopy shows that the Ce-doped BST films display significant decrease in non-perovskited structure. Atomic force microscope presents that the Ce-doped BST films are smooth and dense. The dielectric properties measurement reveals that the Ce-doped BST films show marked improvement in dielectric properties. The tunability can reach 60.8% at 40 V, and the dielectric loss (tand) is 0.0265 at zero bias. Also, the related mechanism of Ce doping for improvement of structure and dielectric properties is presented.