真空科学与技术学报
真空科學與技術學報
진공과학여기술학보
JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY
2009年
6期
664-668
,共5页
马进%吴臣国%吴佩璇%王三坡%沈杰
馬進%吳臣國%吳珮璇%王三坡%瀋傑
마진%오신국%오패선%왕삼파%침걸
等离子体%表面改性%聚酰亚胺%亲水性%剥离强度
等離子體%錶麵改性%聚酰亞胺%親水性%剝離彊度
등리자체%표면개성%취선아알%친수성%박리강도
Plasma%Surface modification%Polyimide%Hydrophilicity%Peel strength
等离子体轰击聚酰亚胺表面会提高挠性印制电路板中溅射铜膜与聚酰亚胺基板的附着力,同时聚酰亚胺表面亲水性随之改变.本文通过改变轰击等离子体种类、轰击电流、轰击时间和轰击气压等条件,研究这些工艺参数与聚酰亚胺表面亲水性的相互关系.在等离子体轰击处理后的聚酰亚胺上磁控溅射镀铜并电镀加厚,利用剥离强度测试仪测量铜膜与聚酰亚胺基板的附着力,并分析亲水性与附着力之间的关系.研究发现,等离子体轰击可以增强聚酰亚胺的亲水性及聚酰亚胺基板与铜膜的附着力,且亲水性越好的样品,溅射镀铜后铜膜与基板的附着力也越好,并得到了等离子体轰击参数与亲水性的关系;研究表明可以把测量亲水性作为聚酰亚胺表面等离子体轰击效果的一种评价方法.
等離子體轟擊聚酰亞胺錶麵會提高撓性印製電路闆中濺射銅膜與聚酰亞胺基闆的附著力,同時聚酰亞胺錶麵親水性隨之改變.本文通過改變轟擊等離子體種類、轟擊電流、轟擊時間和轟擊氣壓等條件,研究這些工藝參數與聚酰亞胺錶麵親水性的相互關繫.在等離子體轟擊處理後的聚酰亞胺上磁控濺射鍍銅併電鍍加厚,利用剝離彊度測試儀測量銅膜與聚酰亞胺基闆的附著力,併分析親水性與附著力之間的關繫.研究髮現,等離子體轟擊可以增彊聚酰亞胺的親水性及聚酰亞胺基闆與銅膜的附著力,且親水性越好的樣品,濺射鍍銅後銅膜與基闆的附著力也越好,併得到瞭等離子體轟擊參數與親水性的關繫;研究錶明可以把測量親水性作為聚酰亞胺錶麵等離子體轟擊效果的一種評價方法.
등리자체굉격취선아알표면회제고뇨성인제전로판중천사동막여취선아알기판적부착력,동시취선아알표면친수성수지개변.본문통과개변굉격등리자체충류、굉격전류、굉격시간화굉격기압등조건,연구저사공예삼수여취선아알표면친수성적상호관계.재등리자체굉격처리후적취선아알상자공천사도동병전도가후,이용박리강도측시의측량동막여취선아알기판적부착력,병분석친수성여부착력지간적관계.연구발현,등리자체굉격가이증강취선아알적친수성급취선아알기판여동막적부착력,차친수성월호적양품,천사도동후동막여기판적부착력야월호,병득도료등리자체굉격삼수여친수성적관계;연구표명가이파측량친수성작위취선아알표면등리자체굉격효과적일충평개방법.
A novel technique was developed to improve the hydrophilicity of polyimide surface and to enhance its interfacial adhesion to Cu film.In the technique,polyimide surfaces were modified by plasma bombardment.The impacts of the surface modification conditions,including type of plasma,bombardment current,time and pressure,on its hydrophilicity were sludied.In addition,the Cu films were deposited on the surface modified polyimide substrate.The results show that plasma surface modification significantly improves its hydrophilicity and its interfacial adhesion.Interesting finding is that the higher the hydrophilicity,the stronger the interfacial adhesion.We suggest that a judicious choiec of plasma surface modification conditions may lead to an optimized hydrophilicity.