发光学报
髮光學報
발광학보
CHINESE JOURNAL OF LUMINESCENCE
2011年
4期
363-367
,共5页
何涛%陈耀%李辉%戴隆贵%王小丽%徐培强%王文新%陈弘
何濤%陳耀%李輝%戴隆貴%王小麗%徐培彊%王文新%陳弘
하도%진요%리휘%대륭귀%왕소려%서배강%왕문신%진홍
GaN%各向异性%X射线衍射%AlN%缓冲层
GaN%各嚮異性%X射線衍射%AlN%緩遲層
GaN%각향이성%X사선연사%AlN%완충층
GaN%anisotropy%XRD%AIN%buffer layer
采用两步AlN缓冲层(一层低温AlN和一层高温AlN)在r面蓝宝石衬底上生长了非极性的α面GaN,并利用高分辨X射线衍射和光致荧光谱对所生长的材料进行了研究.两步AIN缓冲层在我们之前的工作中已被证明比单步高温AlN或低温GaN缓冲层更有利于减小材料各向异性和提高晶体质量,本文进一步优化了两步AlN缓冲层的结构,并得到了各向异性更小,晶体质量更好的α面GaN薄膜.分析表明,两步AlN缓冲层中的低温AlN层在减小各向异性中起着关键作用.低温AlN层能抑制了优势方向(c轴)的原子迁移,有利于劣势方向(m轴)的原子迁移,从而减小了Al原子在不同方向迁移能力的差异,并为其后的高温AlN缓冲层和GaN层提供"生长模板",以得到各向异性更小、晶体质量更好的α面GaN材料.
採用兩步AlN緩遲層(一層低溫AlN和一層高溫AlN)在r麵藍寶石襯底上生長瞭非極性的α麵GaN,併利用高分辨X射線衍射和光緻熒光譜對所生長的材料進行瞭研究.兩步AIN緩遲層在我們之前的工作中已被證明比單步高溫AlN或低溫GaN緩遲層更有利于減小材料各嚮異性和提高晶體質量,本文進一步優化瞭兩步AlN緩遲層的結構,併得到瞭各嚮異性更小,晶體質量更好的α麵GaN薄膜.分析錶明,兩步AlN緩遲層中的低溫AlN層在減小各嚮異性中起著關鍵作用.低溫AlN層能抑製瞭優勢方嚮(c軸)的原子遷移,有利于劣勢方嚮(m軸)的原子遷移,從而減小瞭Al原子在不同方嚮遷移能力的差異,併為其後的高溫AlN緩遲層和GaN層提供"生長模闆",以得到各嚮異性更小、晶體質量更好的α麵GaN材料.
채용량보AlN완충층(일층저온AlN화일층고온AlN)재r면람보석츤저상생장료비겁성적α면GaN,병이용고분변X사선연사화광치형광보대소생장적재료진행료연구.량보AIN완충층재아문지전적공작중이피증명비단보고온AlN혹저온GaN완충층경유리우감소재료각향이성화제고정체질량,본문진일보우화료량보AlN완충층적결구,병득도료각향이성경소,정체질량경호적α면GaN박막.분석표명,량보AlN완충층중적저온AlN층재감소각향이성중기착관건작용.저온AlN층능억제료우세방향(c축)적원자천이,유리우열세방향(m축)적원자천이,종이감소료Al원자재불동방향천이능력적차이,병위기후적고온AlN완충층화GaN층제공"생장모판",이득도각향이성경소、정체질량경호적α면GaN재료.
Nonpolar (11(2)0) a-plane GaN films with two-step AIN buffer(a low-temperature (LT) and a high-temperature (HT) AlN layers) were grown on (1(1)02) r-plane sapphire by metalorganic chemical vapor deposition (MOCYD). The as-grown films were investigated by high-resolution X-ray diffraction (XRD) and photoluminescence (PL). The two-step AlN buffer has been proved to be advantageous in crystal quality compared with one-step LT-GaN or HT-AlN buffers in our early works. In this report, the thickness of the two-step buffer was further optimized, and much less anisotropic a-plane GaN flms were achieved. It was found that the LT-AIN layer of the two-step buffer played a key role in reduction of anisotropy of the GaN film grown.