CAJ | 학술논문

以5 W/％稀HCl溶液对各类城市生活垃圾衍生燃料(RDF)及其组分进行处理，考察在不同温度下快速热解生成半焦的动力学参数变化，并对半焦的比表面积和孔体积的变化和分形维数进行分析研究。试验结果发现酸洗后RDF热解速率提高，活化能降低。酸洗后半焦的比表面积和孔体积均有所减小，并随热解温度先升高而后下降，在450℃附近出现极大值。对半焦的分形维数分析表明，酸洗后表面变得光滑，形成欧氏平面。
이5 W/％희HCl용액대각류성시생활랄급연생연료(RDF)급기조분진행처리，고찰재불동온도하쾌속열 해생성반초적동역학삼수변화，병대반초적비표면적화공체적적변화화분형유수진행분석연구。시험결과발현산 세후RDF열해속솔제고，활화능강저。산세후반초적비표면적화공체적균유소감소，병수열해온도선승고이후하 강，재450℃부근출현겁대치。대반초적분형유수분석표명，산세후표면변득광활，형성구씨평면。
Refuse derived fuel (RDF) and its components were treated by 5% HC1 and the changes of kinetic parameters for rapid pyrolysis under different temperature were discussed. The changes of the specific surface area (SSA), pore volume (PV) and fractal dimension for residue were also investigated and analyzed in this paper. The experiment results show that the pyrolysis rate increases and activate energy decreases for RDF after acid treatment. SSA and PV of RDF vary with the reaction temperature during rapid pyrolysis. With increasing temperature, the SSA and PV of acid treated RDF residue rise in the beginning and down in the end. The maximum value appears near 450℃. Further more, the fractal feature of acid treated RDF residue is also discussed. The surface of residue seems smoother and form Euclidean plane after acid treatment.