CAJ | 학술논문

合成了标题化合物.该化合物的分子式[Ni(TSSB)(Bipy)H2O](4H2O(C19H27NiN3O9S), 分子量532.21,采用单色化的MoKα (λ = 0.71073A。)射线测定,共收集15601个数据,其中独立衍射点5371个 (Rint = 0.0316),I > 2σ(I)可观测点数3537个, 结果表明该化合物属单斜晶系,空间群P21/c,其晶胞参数为:a = 16.406(2),b = 15.409(2),c = 9.252(1)A。;β= 90.373°, V = 2338.9(6) A。3, Z = 4, Dc = 1.511 g/cm3,μ = 0.973 mm-1,F(000) = 1112,该配合物是六配位的变形八面体构型.
합성료표제화합물.해화합물적분자식[Ni(TSSB)(Bipy)H2O](4H2O(C19H27NiN3O9S), 분자량532.21,채용단색화적MoKα (λ = 0.71073A。)사선측정,공수집15601개수거,기중독립연사점5371개 (Rint = 0.0316),I > 2σ(I)가관측점수3537개, 결과표명해화합물속단사정계,공간군P21/c,기정포삼수위:a = 16.406(2),b = 15.409(2),c = 9.252(1)A。;β= 90.373°, V = 2338.9(6) A。3, Z = 4, Dc = 1.511 g/cm3,μ = 0.973 mm-1,F(000) = 1112,해배합물시륙배위적변형팔면체구형.