CAJ | 학술논문

文献中有关有机分子在介质中的光顺-反异构化反应有很多的报道.研究的结果表明:所有的例子都存在着"呼拉"扭转反应机制.这一结论是与曾报道过的有关体积守恒理论相一致.所以,这种介质的包围将对溶液中底物的光顺-反异构化反应产生很大的影响(这也是超分子作用之一).
문헌중유관유궤분자재개질중적광순-반이구화반응유흔다적보도.연구적결과표명:소유적례자도존재착"호랍"뉴전반응궤제.저일결론시여증보도과적유관체적수항이론상일치.소이,저충개질적포위장대용액중저물적광순-반이구화반응산생흔대적영향(저야시초분자작용지일).
Literature examples of photoisomerization involving organic compounds under confined conditions are summarized.They are shown to be consistent with the Hula-twist mechanism of isomerization.Thus,the results support the theory that such a volume-conserving reaction mechanism is favored for photoreactions of substrates under conditions where the medium plays a significant role,i.e.,a supramoleclar process.