结构化学
結構化學
결구화학
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2003年
4期
491-494
,共4页
崔小兵%郑寿添%丁兰%丁红%杨国昱
崔小兵%鄭壽添%丁蘭%丁紅%楊國昱
최소병%정수첨%정란%정홍%양국욱
金属-氧簇合物%微孔材料%水热合成%晶体结构%钒%铜
金屬-氧簇閤物%微孔材料%水熱閤成%晶體結構%釩%銅
금속-양족합물%미공재료%수열합성%정체결구%범%동
合成了标题化合物[Cu(enMe)2]4[H5VⅣ18O42(Cl)]·8H2O 1,晶体属于四方晶系,P4/nnc空间群,晶胞参数a = 15.0034(3), c = 18.8149(3) (A。), V = 4235.27(14) (A。)3, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, μ= 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)max = 0.969×103 , (Δρ)min = -0.454×103 e/(A。)3.化合物1的阴离子[VⅣ18O42(Cl)]8-通过金属配合物阳离子[Cu(enMe)2]2+连接形成3-D骨架结构.
閤成瞭標題化閤物[Cu(enMe)2]4[H5VⅣ18O42(Cl)]·8H2O 1,晶體屬于四方晶繫,P4/nnc空間群,晶胞參數a = 15.0034(3), c = 18.8149(3) (A。), V = 4235.27(14) (A。)3, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, μ= 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)max = 0.969×103 , (Δρ)min = -0.454×103 e/(A。)3.化閤物1的陰離子[VⅣ18O42(Cl)]8-通過金屬配閤物暘離子[Cu(enMe)2]2+連接形成3-D骨架結構.
합성료표제화합물[Cu(enMe)2]4[H5VⅣ18O42(Cl)]·8H2O 1,정체속우사방정계,P4/nnc공간군,정포삼수a = 15.0034(3), c = 18.8149(3) (A。), V = 4235.27(14) (A。)3, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, μ= 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Δρ)max = 0.969×103 , (Δρ)min = -0.454×103 e/(A。)3.화합물1적음리자[VⅣ18O42(Cl)]8-통과금속배합물양리자[Cu(enMe)2]2+련접형성3-D골가결구.
