一个二核钒配合物的合成及晶体结构:NH4[(VⅣO)2(μ2-O)(nta)2][[EuⅢ(H2O)9]
일개이핵범배합물적합성급정체결구:NH4[(VⅣO)2(μ2-O)(nta)2][[EuⅢ(H2O)9]
Synthesis and Crystal Structure of a Binuclear Vanadium Complex:NH4[(VⅣO)2(μ2-O)(nta)2] [EuⅢ(H2O)9]
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2005年 1期 101-104 ,共4页

    张全争%陈淑妹%余雅琴%何翔%闫莹%刘九辉%许新江%夏昌坤%陈丽娟%吴小园%卢灿忠

    장전쟁%진숙매%여아금%하상%염형%류구휘%허신강%하창곤%진려연%오소완%로찬충

    氮三乙酸%钒%合成和晶体结构 氮三乙痠%釩%閤成和晶體結構
    담삼을산%범%합성화정체결구
    nitrilotriacetic acid%vanadium%synthesis and crystal structure


    A binuclear vanadium complex NH4[(VⅣO)2( μ2-O)(nta)2] [Eu Ⅲ(H2O)9] was synthesized by reaction of NH3VO3, nitrilotriacetic acid and EuC13 in one aqueous solution. The crystal X-ray analysis shows that the complex contains one binuclear vanadium anion [(VⅣO)2( μ2-O)(nta)2]4- and one [EuⅢ(H2O)9]3+ cation. The molecules are built up to a three-dimensional supramolecular structure through hydrogen bonding. CCDC: 238716.
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