物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2008年
6期
945-950
,共6页
速率常数%·0H%还原态硫化物
速率常數%·0H%還原態硫化物
속솔상수%·0H%환원태류화물
Rate constant%·OH%Reduced sulfur compound
利用180-L Teflon气袋,采用相对速率方法测定了298K,1.013×105Pa条件下·OH自由基与6种还原态硫化物在空气、氮气和氧气体系下的反应速率常数.所得结果与文献值进行了比较,并讨论了氧气对速率常数的影响.
利用180-L Teflon氣袋,採用相對速率方法測定瞭298K,1.013×105Pa條件下·OH自由基與6種還原態硫化物在空氣、氮氣和氧氣體繫下的反應速率常數.所得結果與文獻值進行瞭比較,併討論瞭氧氣對速率常數的影響.
이용180-L Teflon기대,채용상대속솔방법측정료298K,1.013×105Pa조건하·OH자유기여6충환원태류화물재공기、담기화양기체계하적반응속솔상수.소득결과여문헌치진행료비교,병토론료양기대속솔상수적영향.
The rate constants for the reactions between ·OH and six reduced sulfur compounds in air, N2, and O2 were measured using relative rate constant method in a 180-L Teflon bag at 298K and 1.013×105Pa. These results were compared with previous published data and were discussed in terms of trends in different buffer gases.
