新型一维钼氧链超分子化合物[(H2bpe)Mo4O13]的合成与光学性质研究
신형일유목양련초분자화합물[(H2bpe)Mo4O13]적합성여광학성질연구
Hydrothermal Synthesis,Characterization and Luminescence Property of a New 1D Molybdenum Oxide Chain:[(H2bpe)Mo4O13]
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2010年 5期 921-925 ,共5页

    吴晶晶%韩占刚%王彦娜%郝青华%翟学良

    오정정%한점강%왕언나%학청화%적학량

    钼氧链%晶体结构%光学性质 鉬氧鏈%晶體結構%光學性質
    목양련%정체결구%광학성질
    molybdenum oxide chain%crystal structure%lumineseent property


    A new 1D compound[(H2bpe)Mo4O13](1)(bpe=trans-1,2-Di-(4-pyridyl)-ethylen) was hydrothermally synthesized and characterized.Compound 1 comprises 3D supramolecular network constructed from 1D[Mo4O13]2-anion chains and protonated bpo layers via hydrogen bonds and π-πstacking interactions.The crystal data are the following:C12H12Mo4N2O13,Monoclinic,space group P21/n,a=0.968 64(13)nm,b=1.349 68(18)nm,c=1.514 9(2)nm,β=99.766(2)°,Z=4.The inorganic chain built up from only molybdenum oxide building blocks is interesting.The luminescent property of 1 was studied.CCDC:739954.
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