CAJ | 학술논문

以4-硝基邻苯二腈、二水醋酸锌为原料，离子液体[bmim]BF4为溶剂，一步反应合成β-四硝基酞菁锌。通过JR光谱、UV—Vis光谱表征了其结构，采用单因素实验对影响β-四硝基酞菁锌收率的主要因素进行了考察。结果表明：反应温度140℃，反应时间4h，m（[bmim]BF4）／m（4-硝基邻苯二腈）：10：1为最佳条件。采用本法合成金属酞菁，反应条件易控、无需回流、简化了实验过程，提高了合成效率。
이4-초기린분이정、이수작산자위원료，리자액체[bmim]BF4위용제，일보반응합성β-사초기태정자。통과JR광보、UV—Vis광보표정료기결구，채용단인소실험대영향β-사초기태정자수솔적주요인소진행료고찰。결과표명：반응온도140℃，반응시간4h，m（[bmim]BF4）／m（4-초기린분이정）：10：1위최가조건。채용본법합성금속태정，반응조건역공、무수회류、간화료실험과정，제고료합성효솔。
Using 4 -nitrophthalonitrile ,ZnAc · 2H2O as starting materials in ionic liquid [ bmim] BF4, β- tetranitrophthalocyanine zinc was synthesized in one - step reaction. The product was characterized by the methods of IR and UV - Vis spectroscopy. The main factors which affected the yield of β- tetranitrophthalocyanine zinc were also investigated by the single factor experiments. The results indicated that the optimal conditions were shown as follows ,temperature： 140℃, time： 4 h ,mass ratio of [ bmim] BF4）/4- nitrophthalonitrile： 10： 1. Using this method, the reaction conditions were easily controlled without reflux, the procedure was simplified and the synthetic efficiency was improved.