兵器材料科学与工程
兵器材料科學與工程
병기재료과학여공정
Ordnance Material Science and Engineering
2010年
2期
23-26
,共4页
花兴艳%赵培仲%朱金华%王源升
花興豔%趙培仲%硃金華%王源升
화흥염%조배중%주금화%왕원승
聚氨酯/环氧树脂互穿聚合物网络%半硬泡沫%静态压缩%本构关系
聚氨酯/環氧樹脂互穿聚閤物網絡%半硬泡沫%靜態壓縮%本構關繫
취안지/배양수지호천취합물망락%반경포말%정태압축%본구관계
polyurethane/epoxy interpenetrating polymer network%semirigid foam%static compression%constitutive relation
采用同步法合成聚氨酯/环氧树脂互穿聚合物网络(PU/ER IPN)半硬泡沫.对IPN半硬泡沫进行了应变率在1.67×10~(-4)~1.67×10~(-2) s~(-1)范围内的静态压缩实验.研究表明,泡沫在平行发泡方向和垂直发泡方向上压缩应力一应变曲线没有明显区别.平行方向上的压缩应力-应变曲线表现出3个变形阶段:弹性阶段,"平台"阶段和"硬化"密实阶段.应力-应变曲线单调增加,平台阶段没有产生应变软化,整个压缩过程中试样变形是均匀分布的.IPN半硬泡沫材料在静态实验中存在明显的应变率效应.讨论IPN半硬泡沫的压缩力学本构关系.
採用同步法閤成聚氨酯/環氧樹脂互穿聚閤物網絡(PU/ER IPN)半硬泡沫.對IPN半硬泡沫進行瞭應變率在1.67×10~(-4)~1.67×10~(-2) s~(-1)範圍內的靜態壓縮實驗.研究錶明,泡沫在平行髮泡方嚮和垂直髮泡方嚮上壓縮應力一應變麯線沒有明顯區彆.平行方嚮上的壓縮應力-應變麯線錶現齣3箇變形階段:彈性階段,"平檯"階段和"硬化"密實階段.應力-應變麯線單調增加,平檯階段沒有產生應變軟化,整箇壓縮過程中試樣變形是均勻分佈的.IPN半硬泡沫材料在靜態實驗中存在明顯的應變率效應.討論IPN半硬泡沫的壓縮力學本構關繫.
채용동보법합성취안지/배양수지호천취합물망락(PU/ER IPN)반경포말.대IPN반경포말진행료응변솔재1.67×10~(-4)~1.67×10~(-2) s~(-1)범위내적정태압축실험.연구표명,포말재평행발포방향화수직발포방향상압축응력일응변곡선몰유명현구별.평행방향상적압축응력-응변곡선표현출3개변형계단:탄성계단,"평태"계단화"경화"밀실계단.응력-응변곡선단조증가,평태계단몰유산생응변연화,정개압축과정중시양변형시균균분포적.IPN반경포말재료재정태실험중존재명현적응변솔효응.토론IPN반경포말적압축역학본구관계.
A series of semirigid interpenetrating polymer networks foams,based on polyurethane and epoxy resin,were prepared by a simultaneous polymerization technique.The compression stress-strain behaviors of the simirigid polyurethane/epoxy interpenetrating polymer networks(PU/ER IPN)foams were tested at strain rate of 1.67×10~(-4)-1.67×10~(-2) s~(-1).The compression stress-strain responses of the IPN foam in the rising and transversal directions were almost identical.Compression in the two directions yields a three-stage stress-strain response-an initial linear elastic response,a protracted plateau and a final sharp rise in compressive stress,gives rise to a monotonously increasing stress-strain curve without strain-softening and always produces uniformly distributed deformation.Experimental results show that the compression behaviors of the IPN foams are sensitive to the strain-rates.The constitutive relation describing the compression behavior was discussed.