硅酸盐学报
硅痠鹽學報
규산염학보
JOURNAL OF THE CHINESE CERAMIC SOCIETY
2007年
11期
1535-1537
,共3页
贾宝申%赵业权%申岩%何焰蓝
賈寶申%趙業權%申巖%何燄藍
가보신%조업권%신암%하염람
近化学计量比%铌酸锂%吸收光谱%衍射效率%顶部籽晶法
近化學計量比%鈮痠鋰%吸收光譜%衍射效率%頂部籽晶法
근화학계량비%니산리%흡수광보%연사효솔%정부자정법
near stoichiometric%lithium niobate%absorption spectrum%photorefractive effect%top-seed solution method
采用助熔剂提拉法,从掺入0.1%(摩尔分数)Fe2O3,0.2% MnO和11.2% K2CO3的同成分LiNbO3熔体中生长出高质量近化学计量比Mn:Fe:LiNbO3晶体.采用提拉法生长了相同掺杂的同成分晶体.与同成分晶体相比较,近化学计量比晶体的紫外吸收发生紫移,红外吸收变窄.利用二波耦合光路测试了晶体的衍射效率、增益系数和响应时间.结果显示:近化学计量比晶体的增益系数和衍射效率分别达到25 cm-1和68.3%,响应时间为亚秒级.
採用助鎔劑提拉法,從摻入0.1%(摩爾分數)Fe2O3,0.2% MnO和11.2% K2CO3的同成分LiNbO3鎔體中生長齣高質量近化學計量比Mn:Fe:LiNbO3晶體.採用提拉法生長瞭相同摻雜的同成分晶體.與同成分晶體相比較,近化學計量比晶體的紫外吸收髮生紫移,紅外吸收變窄.利用二波耦閤光路測試瞭晶體的衍射效率、增益繫數和響應時間.結果顯示:近化學計量比晶體的增益繫數和衍射效率分彆達到25 cm-1和68.3%,響應時間為亞秒級.
채용조용제제랍법,종참입0.1%(마이분수)Fe2O3,0.2% MnO화11.2% K2CO3적동성분LiNbO3용체중생장출고질량근화학계량비Mn:Fe:LiNbO3정체.채용제랍법생장료상동참잡적동성분정체.여동성분정체상비교,근화학계량비정체적자외흡수발생자이,홍외흡수변착.이용이파우합광로측시료정체적연사효솔、증익계수화향응시간.결과현시:근화학계량비정체적증익계수화연사효솔분별체도25 cm-1화68.3%,향응시간위아초급.
Near stoichiometric lithium niobate crystal doped with 0.1% (molar fraction, the same bellow) Fe2O3 and 0.2%MnO and 11.2% K2CO3 was grown by the flux method and congruent crystal with the same dopants was grown by Czochralski method. The crystals were characterized by ultraviolet absorption edge, and infrared spectra. The crystal has a shift in absorption towards shorter wavelength and infrared absorption peak shifts to smaller to form a sharp band. The exponential gain coefficient, diffraction efficiency and response time were measured by a two-wave coupling method. The results indicate that the exponential gain coefficient and diffraction efficiency of the near stoichiometric crystal reach to 25 cm-1 and 68.3%,respectively, while response time is less than 1 second.