合成化学
閤成化學
합성화학
CHINESE JOURNAL OF SYNTHETIC CHEMISTRY
2004年
5期
495-498
,共4页
合成%配体%2-苯基茚
閤成%配體%2-苯基茚
합성%배체%2-분기인
synthesis%ligard%2-phenylindeny
采用Schlenk技术,在干燥纯氩气保护下,用无水三氯化稀土LnCl3与等摩尔的2-苯基茚(2-PhInd)锂盐在THF中反应,得到8种未见报道的稀土金属有机配合物:(2-PhInd)LnCl2 .所有配合物都经元素分析、IR和MS表征,并推测出其可能的分子结构.
採用Schlenk技術,在榦燥純氬氣保護下,用無水三氯化稀土LnCl3與等摩爾的2-苯基茚(2-PhInd)鋰鹽在THF中反應,得到8種未見報道的稀土金屬有機配閤物:(2-PhInd)LnCl2 .所有配閤物都經元素分析、IR和MS錶徵,併推測齣其可能的分子結構.
채용Schlenk기술,재간조순아기보호하,용무수삼록화희토LnCl3여등마이적2-분기인(2-PhInd)리염재THF중반응,득도8충미견보도적희토금속유궤배합물:(2-PhInd)LnCl2 .소유배합물도경원소분석、IR화MS표정,병추측출기가능적분자결구.
Reaction of LnCl3 with one equivalent 2-phenylindeny(2-PhInd) lithium in THF resulted in eight new organolanthanide complexes:(2-PhInd)LnCl2 . All the complexes were characterized by elemental analysis, IR, MS and their possible structures were deduced.
